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磷氮化合物 - （第50部分）：含二茂铁侧臂的环磷腈衍生物结构参数之间的相关性

Phosphorus-nitrogen compounds- (Part 50): correlations between structural parameters for cylophosphazene derivatives containing ferrocenyl pendant arm(s).

作者信息

Asmafİlİz Nuran, Elmas Gamze, OkumuŞ Aytuğ, Bİlge KoÇak Selen, KiliÇ Zeynel

机构信息

Department of Chemistry, Faculty of Science, Ankara University, Ankara Turkey.

出版信息

Turk J Chem. 2020 Jun 1;44(3):543-558. doi: 10.3906/kim-1909-83. eCollection 2020.

DOI:10.3906/kim-1909-83
PMID:33488176
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7671203/
Abstract

The results of a systematic study of -cyclotri/tetraphosphazenes with ferrocenyl pendant arm on the basis of correlation between structural parameters were presented. The main parameters were obtained from Xray crystallography and P NMR results in order to investigate the relationship between the δ P shift values and endocyclic and exocyclic NPN bond angles, and electron density transfer parameters. Structural parameters derived from 11 types of the ferrocenyl cyclophosphazene derivatives with 5- to 7-membered -rings introduced to the literature from our research group were studied and compared with each other.

摘要

基于结构参数之间的相关性，给出了对带有二茂铁基侧链的环三/四磷腈的系统研究结果。为了研究δP位移值与环内和环外NPN键角以及电子密度转移参数之间的关系，主要参数是从X射线晶体学和磷核磁共振结果中获得的。对我们研究小组引入文献的11种带有5至7元环的二茂铁基环磷腈衍生物的结构参数进行了研究并相互比较。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a71/7671203/bbd2bebacd1a/turkjchem-44-543-fig003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a71/7671203/01ae2d4b0cc8/turkjchem-44-543-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a71/7671203/17fad5e9fa7d/turkjchem-44-543-fig001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a71/7671203/37485594e4eb/turkjchem-44-543-fig002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a71/7671203/bbd2bebacd1a/turkjchem-44-543-fig003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a71/7671203/01ae2d4b0cc8/turkjchem-44-543-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a71/7671203/17fad5e9fa7d/turkjchem-44-543-fig001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a71/7671203/37485594e4eb/turkjchem-44-543-fig002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a71/7671203/bbd2bebacd1a/turkjchem-44-543-fig003.jpg

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J Fluoresc. 2016 Jul;26(4):1173-81. doi: 10.1007/s10895-016-1797-0. Epub 2016 Apr 16.
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Phosphorus-nitrogen compounds: part 30. Syntheses and structural investigations, antimicrobial and cytotoxic activities and DNA interactions of vanillinato-substituted NN or NO spirocyclic monoferrocenyl cyclotriphosphazenes.磷氮化合物：第30部分。香草酸取代的NN或NO螺环单茂铁基环三磷腈的合成、结构研究、抗菌和细胞毒性活性以及与DNA的相互作用
J Biol Inorg Chem. 2015 Jan;20(1):165-178. doi: 10.1007/s00775-014-1223-5. Epub 2014 Dec 10.
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Phosphorus-nitrogen compounds. Part 29. Syntheses, crystal structures, spectroscopic and stereogenic properties, electrochemical investigations, antituberculosis, antimicrobial and cytotoxic activities and DNA interactions of ansa-spiro-ansa cyclotetraphosphazenes.磷氮化合物。第29部分。桥联-螺-桥联环四磷腈的合成、晶体结构、光谱和立体化学性质、电化学研究、抗结核、抗菌和细胞毒性活性以及与DNA的相互作用
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4
Chiral multidentate oxazoline ligands based on cyclophosphazene cores: synthesis, characterization and complexation studies.基于环磷腈核的手性多齿恶唑啉配体：合成、表征及络合研究
Dalton Trans. 2014 Oct 7;43(37):13899-912. doi: 10.1039/c4dt01741b. Epub 2014 Aug 11.
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Synthesis, cytotoxicity and apoptosis of cyclotriphosphazene compounds as anti-cancer agents.作为抗癌剂的环三磷腈化合物的合成、细胞毒性和细胞凋亡。
Eur J Med Chem. 2012 Jun;52:213-20. doi: 10.1016/j.ejmech.2012.03.018. Epub 2012 Mar 19.
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Ring-closing metathesis reactions of terminal alkene-derived cyclic phosphazenes.末端烯烃衍生环状膦嗪的环 closing 复分解反应。
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Inorg Chem. 2006 Oct 16;45(21):8755-67. doi: 10.1021/ic060630n.