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氧化镁催化壳聚糖转化为乳酸。

Magnesium Oxide-Catalyzed Conversion of Chitin to Lactic Acid.

机构信息

Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology (AIST), 4-2-1 Nigatake, Miyagino, Sendai, 983-8551, Japan.

Department of Chemical Technology, Faculty of Science, Chulalongkorn University Pathumwan, Bangkok, 10330, Thailand.

出版信息

ChemistryOpen. 2021 Mar;10(3):308-315. doi: 10.1002/open.202000303. Epub 2021 Jan 25.


DOI:10.1002/open.202000303
PMID:33492785
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7953471/
Abstract

Although chitin, an N-acetyl-D-glucosamine polysaccharide, can be converted to valuable products by means of homogeneous catalysis, most of the chitin generated by food processing is treated as industrial waste. Thus, a method for converting this abundant source of biomass to useful chemicals, such as lactic acid, would be beneficial. In this study, we determined the catalytic activities of various metal oxides for chitin conversion at 533 K and found that MgO showed the highest activity for lactic acid production. X-ray diffraction analysis and thermogravimetry-differential thermal analysis showed that the MgO was transformed to Mg(OH) during chitin conversion. The highest yield of lactic acid (10.8 %) was obtained when the reaction was carried out for 6 h with 0.5 g of the MgO catalyst. The catalyst could be recovered as a solid residue after the reaction and reused twice with no decrease in the lactic acid yield.

摘要

尽管壳聚糖是一种 N-乙酰-D-葡萄糖胺多糖,可以通过均相催化转化为有价值的产品,但食品加工过程中产生的大部分壳聚糖都被视为工业废物。因此,将这种丰富的生物质资源转化为有用的化学品(如乳酸)的方法将是有益的。在这项研究中,我们在 533K 下测定了各种金属氧化物对壳聚糖转化的催化活性,发现 MgO 对乳酸生产表现出最高的活性。X 射线衍射分析和热重-差示热分析表明,在壳聚糖转化过程中,MgO 转化为 Mg(OH)。当反应在 0.5g 的 MgO 催化剂下进行 6 小时时,乳酸的最高收率(10.8%)。反应后,催化剂可以作为固体残渣回收,并重复使用两次,乳酸收率没有下降。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f100/7953471/867ddb18cade/OPEN-10-308-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f100/7953471/6f3dca8cd2c8/OPEN-10-308-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f100/7953471/b9658f15c705/OPEN-10-308-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f100/7953471/931a2a6c62fd/OPEN-10-308-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f100/7953471/f47de44751bc/OPEN-10-308-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f100/7953471/2d8d189d83d9/OPEN-10-308-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f100/7953471/867ddb18cade/OPEN-10-308-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f100/7953471/6f3dca8cd2c8/OPEN-10-308-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f100/7953471/b9658f15c705/OPEN-10-308-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f100/7953471/931a2a6c62fd/OPEN-10-308-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f100/7953471/f47de44751bc/OPEN-10-308-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f100/7953471/2d8d189d83d9/OPEN-10-308-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f100/7953471/867ddb18cade/OPEN-10-308-g007.jpg

相似文献

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Magnesium Oxide-Catalyzed Conversion of Chitin to Lactic Acid.

ChemistryOpen. 2021-3

[2]
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[3]
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[4]
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[5]
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[6]
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[7]
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[8]
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[9]
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[10]
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本文引用的文献

[1]
Extraction, chemical modification and characterization of chitin and chitosan.

Int J Biol Macromol. 2018-8-30

[2]
Selective conversion of chitosan to levulinic acid catalysed by acidic ionic liquid: Intriguing NH effect in comparison with cellulose.

Carbohydr Polym. 2018-4-27

[3]
Hydrothermal conversion of N-acetyl-d-glucosamine to 5-hydroxymethylfurfural using ionic liquid as a recycled catalyst in a water-dimethyl sulfoxide mixture.

Carbohydr Res. 2017-4-10

[4]
Shell Biorefinery: Dream or Reality?

Chemistry. 2016-9-12

[5]
Catalytic Depolymerization of Chitin with Retention of N-Acetyl Group.

ChemSusChem. 2015-11

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Sustainability: Don't waste seafood waste.

Nature. 2015-8-13

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Chem Rev. 2011-9-14

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ChemSusChem. 2010-6-21

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