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环氧乳液对不同水化和聚合程度水泥砂浆力学性能及孔隙率性能的影响

Effect of Epoxy Latexes on the Mechanical Behavior and Porosity Property of Cement Mortar with Different Degrees of Hydration and Polymerization.

作者信息

Li Pengfei, Lu Wei, An Xuehui, Zhou Li, Du Sanlin

机构信息

Harbor, Waterway and Coastal Engineering, Chongqing Jiaotong University, Chongqing 400074, China.

State Key Laboratory of Hydroscience and Engineering, Tsinghua University, Beijing 100084, China.

出版信息

Materials (Basel). 2021 Jan 21;14(3):517. doi: 10.3390/ma14030517.

Abstract

In this study, an analysis of the influence of polymer modification on the mechanical behavior, porosity, and microstructure of mortar is carried out. Epoxy latexes contents of 5%, 10%, 15%, and 20% of cement were employed in the preparation of cement mortars based on the same workability. The specimens were subjected to dry, wet, and wet-dry curing regimes. Compressive strength, flexural strength, Mercury intrusion porosimetry (MIP), and scanning electronic microscope (SEM) tests were conducted to analyze the effect of epoxy latexes on the mechanical property and porosity of modified mortars. Based on the compressive strength test results, a quantitative method was established to calculated the degree of hydration and polymerization. The results show that the mechanical behavior and porosity property of epoxy latexes modified mortar are influenced by the degree of hydration, the degree of polymerization, and the volume changing effect of mortar. The polymerization of epoxy latexes could improve the flexural strength of the mortar. The macropores of specimens tended to decrease with the increase of the degree of epoxy latexes polymerization and cement hydration. In practical engineering, it is necessary to ensure the degree of hydration and increase the polymerization rate. Thus, the wet-dry curing regime is recommended.

摘要

在本研究中,对聚合物改性对砂浆力学性能、孔隙率和微观结构的影响进行了分析。基于相同的工作性,在制备水泥砂浆时采用了占水泥5%、10%、15%和20%的环氧乳液含量。对试件进行了干燥、潮湿和干湿循环养护制度。进行了抗压强度、抗折强度、压汞法(MIP)和扫描电子显微镜(SEM)试验,以分析环氧乳液对改性砂浆力学性能和孔隙率的影响。基于抗压强度试验结果,建立了一种定量方法来计算水化程度和聚合程度。结果表明,环氧乳液改性砂浆的力学性能和孔隙率特性受水化程度、聚合程度和砂浆体积变化效应的影响。环氧乳液的聚合可以提高砂浆的抗折强度。随着环氧乳液聚合程度和水泥水化程度的增加,试件的大孔趋于减少。在实际工程中,有必要确保水化程度并提高聚合速率。因此,推荐采用干湿循环养护制度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0a44/7865887/cb37f87692c6/materials-14-00517-g001.jpg

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