Wang Ming, Jiang Xuefeng
Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, 3663 North Zhongshan Rd., Shanghai, 200062, P. R. China).
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, postcode is missing, Shanghai, P. R. China.
Chem Rec. 2021 Dec;21(12):3338-3355. doi: 10.1002/tcr.202000162. Epub 2021 Jan 26.
Sulfonyl compounds have attracted considerable interest due to their extensive applications in drug discovery, agricultural, and material science. The access to the assembly of SO -containing compounds via the same oxidative-state introduction of hypervalent sulfur has come to the fore in the recent years. Especially, the transition-metal-involved synthesis of hypervalent sulfur compounds is the most effective strategy since SO is easy to insert into the metal-carbon bonds. This review discusses the application of the same oxidation-state introduction of hypervalent sulfur strategy under the transition-metal-catalyzed conditions, and presents according to different metal catalysts and the synthesized diversity hypervalent sulfur-containing compounds skeletons, including sulfonamides, sulfones, sulfinamides, sulfonyl acids and sulfonyl fluorides.
由于磺酰化合物在药物发现、农业和材料科学中的广泛应用，它们引起了人们的极大兴趣。近年来，通过引入相同氧化态的高价硫来构建含硫化合物已成为研究热点。特别是，过渡金属参与的高价硫化合物合成是最有效的策略，因为硫氧双键易于插入金属-碳键中。本文综述了过渡金属催化条件下引入相同氧化态高价硫策略的应用，并根据不同的金属催化剂和合成的多种含高价硫化合物骨架进行阐述，包括磺酰胺、砜、亚磺酰胺、磺酸和磺酰氟。
