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将轴向零场分裂与钆单离子磁体中的慢磁弛豫相关联。

Correlating the axial Zero Field Splitting with the slow magnetic relaxation in Gd SIMs.

作者信息

Mayans Júlia, Escuer Albert

机构信息

Instituto de Ciencia Molecular (ICMol), Universitat de València, Paterna, València 46980, Spain.

Departament de Química Inorgànica i Orgànica, Secció Inorgànica and Institute of Nanoscience (IN2UB) and Nanotecnology, Universitat de Barcelona, Martí i Franquès 1-11, Barcelona-08028, Spain.

出版信息

Chem Commun (Camb). 2021 Jan 26;57(6):721-724. doi: 10.1039/d0cc07474h.

DOI:10.1039/d0cc07474h
PMID:33496705
Abstract

The field-induced out-of-phase magnetic response of a GdIII complex, selected by its good isolation in the network, has been analyzed and the behaviour of this quasi-isotropic cation has been related to its weak axial zero field splitting ∼0.1 cm-1.

摘要

通过在网络中良好的隔离性筛选出的一种GdIII配合物的场致异相磁响应已被分析，并且这种准各向同性阳离子的行为已与约0.1 cm-1的弱轴向零场分裂相关联。

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