Ma Li, Huang Xiao, Sheng Youjie, Liu Xixi, Wei Gaoming
College of Safety Science and Engineering, Xi'an University of Science and Technology, Xi'an 710054, China.
Shaanxi Key Laboratory of Prevention and Control of Coal Fire, Xi'an 710054, China.
Polymers (Basel). 2021 Jan 24;13(3):367. doi: 10.3390/polym13030367.
Hydrogels are crosslinked polymers that become fully swollen when placed in aqueous environments. They are widely used in the field of firefighting because they can remarkably increase the viscosity and wettability of water. In this study, a thermosensitive hydrogel used to effectively suppress class A fire was synthesized by using methylcellulose, sodium polyacrylate, and magnesium chloride. The structure, surface activity and viscosity of the hydrogel were characterized. Fire extinguishing performance was evaluated based on small-scale and large-scale experiments. The results showed that a phase transition of the hydrogel occurred when the temperature rose from 50 °C to 80 °C. After the phase transition, the hydrogel showed a higher viscosity and lower surface tension, which was conducive to attach to the surface of the burning material and acting as an effective barrier to isolate oxygen. The small-scale fire extinguishing tests indicated that the concentration of the hydrogel solution has an eminent influence on fire extinguishing performance. The optimum concentration for extinguishing performance was around 6 wt%. The large-scale experiments demonstrated that the fire-extinguishing performance of this thermosensitive hydrogel was superior to the two other commercial water-based fire extinguishing agents, as it prevented re-ignition highly efficiently.
水凝胶是一种交联聚合物,置于水环境中时会完全溶胀。它们在消防领域有广泛应用,因为能显著提高水的黏度和润湿性。本研究中,通过使用甲基纤维素、聚丙烯酸钠和氯化镁合成了一种用于有效扑灭A类火灾的热敏水凝胶。对该水凝胶的结构、表面活性和黏度进行了表征。基于小规模和大规模实验评估了灭火性能。结果表明,当温度从50℃升至80℃时,水凝胶发生了相变。相变后,水凝胶表现出更高的黏度和更低的表面张力,这有利于附着在燃烧材料表面并作为隔离氧气的有效屏障。小规模灭火试验表明,水凝胶溶液的浓度对灭火性能有显著影响。灭火性能的最佳浓度约为6wt%。大规模实验表明,这种热敏水凝胶的灭火性能优于其他两种商用的水基灭火剂,因为它能高效防止复燃。