Energizing periodic mesoporous organosilica (PMOS) with bismuth and cerium for photo-degrading methylene blue and methyl orange in water.

This work reported an efficient catalyst to reduce the organic pollutants by using an energetic periodic mesoporous organosilica (PMOS) supported with bismuth (Bi-PMOS) and cerium (Ce-PMOS). PMOS support was designed through co-condensation of sodium silicate and 3-methacryloxypropyltrimethoxysilane on polysorbate templates. The resultant PMOSs were fabricated with bismuth and cerium oxides to formulate Bi-PMOS and Ce-PMOS, respectively. These materials showed photo-degradations of methylene blue (MB, 74.7% and 41.1% with Bi-PMOS and Ce-PMOS, respectively) and methyl orange (MO, 53.2% and 39.4% with Bi-PMOS and Ce-PMOS, respectively). Such efficient photo-degradations were attributed to the precise doping of metallic nodes of Bi O and CeO on the porous structure of PMOS with high surface area. The results also showed that Bi and Ce were more effective in PMOS support for photo-degradation of dyes as the support provides more lifetime to photo-generated electron-hole pairs than other materials. Moreover, active reusability and high degradation efficiencies of Bi-PMOS and Ce-PMOS proved them better analytical tools to reduce organic pollutants under visible lights. PRACTITIONER POINTS: The oxides of bismuth and cerium have impressive photocatalytic characteristics. New material energizing mesoporous organosilica with bismuth and cerium for photo-degradation of methylene blue and methyl orange in water. The use of an efficient catalyst to reduce the organic pollutants by using an energetic periodic mesoporous organosilica (PMOS) supported with bismuth (Bi-PMOS) and cerium (Ce-PMOS).