Chen Yao, Liu Xing, Zhou Jian, Zou Hua-Hong, Xiang Bin
Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing 401331, P. R. China.
State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmacy, Guangxi Normal University, Guilin 541004, P. R. China.
Inorg Chem. 2021 Feb 15;60(4):2127-2132. doi: 10.1021/acs.inorgchem.0c03484. Epub 2021 Jan 27.
Two new one-dimensional (1D) vanadium(III) chalcogenidostannates, [Htepa][V(tepa)(μ-SnQ)] [Q = S (), Se (); tepa = tetraethylenepentamine], were achieved by solvothermal methods, which offer the first examples of organic hybrid polymeric chalcogenidostannates incorporating [V(tepa)] complexes as bridging groups. Both and feature the 1D sinusoidal chains of [V(tepa)(μ-SnQ)] containing two types of novel bridging modes of the [μ-SnQ] anion. Their magnetic, photocurrent response, and optical properties are also studied.
通过溶剂热法制备了两种新型的一维（1D）硫族锡酸钒（III）化合物，[Htepa][V(tepa)(μ-SnQ)] [Q = S （），Se （）；tepa = 四乙烯五胺]，它们是首例以[V(tepa)]配合物作为桥联基团的有机杂化聚合物硫族锡酸盐。 和 均具有[V(tepa)(μ-SnQ)]的一维正弦链，其中[μ-SnQ]阴离子具有两种新型桥联模式。还研究了它们的磁性、光电流响应和光学性质。
