Laboratory of Integrated Sciences, Universidade Federal de São Paulo, Prof. Artur Riedel, 275 - Eldorado, Diadema, São Paulo, CEP: 09972-270, Brazil.
Faculdade de Tecnologia SENAI Antônio Skaf, Rua Correia de Andrade Street, São Paulo, CEP 03008-020, Brazil.
Environ Sci Pollut Res Int. 2021 Jun;28(21):27318-27332. doi: 10.1007/s11356-021-12594-6. Epub 2021 Jan 28.
Fabric dyeing produces high amounts of wastewater containing organic and inorganic pollutants such as reactive dyes that are the most common textile dyes employed by the industry. Three vinylsulfonic reactive dyes, blue 19 (B-19), red 198 (R-198), and yellow 15 (Y-15), were removed from effluents of industrial-like dyeing processes employing three adsorbents: (1) magnetite nanoparticles (MNP), (2) yeast waste obtained after β-glucan removal from yeast biomass (YW), and (3) nanomagnetic composite produced from YW and MNP (YW-MNP). The non-linear kinetic pseudo-second-order and two-stage models best explained the experimental phenomena for the majority of adsorbate:adsorbent systems. The theoretical isotherm models were fitted to experimental isotherms obtained from experiments conducted with appropriated dilutions of effluents, which have a specific condition, limited by the maximum dye concentration established by the dye recipe. Thus, the saturation of adsorbents was not reached for all adsorbate:adsorbent systems. In this way, the best conditional sorption capacities (SC) were obtained by YW (1.7, 2.3, and 2.5 g/kg for B-19, R-198, and Y-15, respectively). The SIPS model best described all dyes adsorbed by YW, while the D-R model best described the phenomena for MNP and YW-MNP.
织物染色会产生大量含有有机和无机污染物的废水,例如活性染料,这是工业中最常用的纺织染料。三种乙烯砜基活性染料,蓝色 19(B-19)、红色 198(R-198)和黄色 15(Y-15),从采用三种吸附剂的工业染色过程的废水中被去除:(1)磁铁矿纳米颗粒(MNP),(2)从酵母生物质中去除β-葡聚糖后获得的酵母废料(YW),以及(3)由 YW 和 MNP 制成的纳米磁性复合材料(YW-MNP)。对于大多数吸附物:吸附剂系统,非线性动力学拟二级和两阶段模型最好地解释了实验现象。理论等温模型与通过在适当稀释的废水中进行实验获得的实验等温线拟合,这些废水具有特定的条件,受染料配方规定的最大染料浓度限制。因此,并非所有吸附物:吸附剂系统都达到了吸附剂的饱和。这样,通过 YW 获得了最佳的条件吸附容量(SC)(B-19、R-198 和 Y-15 分别为 1.7、2.3 和 2.5 g/kg)。YW 吸附的所有染料均由 SIPS 模型最佳描述,而 D-R 模型则最好地描述了 MNP 和 YW-MNP 的现象。