4,4,4-三氟丁-2-炔-1-酮向芳香族和杂芳香族化合物的简便制备与转化
Facile preparation and conversion of 4,4,4-trifluorobut-2-yn-1-ones to aromatic and heteroaromatic compounds.
作者信息
Yamazaki Takashi, Nakajima Yoh, Iida Minato, Kawasaki-Takasuka Tomoko
机构信息
Division of Applied Chemistry, Institute of Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Nakamachi, Koganei 184-8588, Japan.
出版信息
Beilstein J Org Chem. 2021 Jan 15;17:132-138. doi: 10.3762/bjoc.17.14. eCollection 2021.
Abstract
The concise preparation of 4,4,4-trifluorobut-2-yn-1-ones by the oxidation of the readily accessible corresponding propargylic alcohols as well as their utilization as Michael acceptors for the construction of aromatic and heteroaromatic compounds are reported.
摘要
报道了通过氧化易于获得的相应炔丙醇来简洁地制备4,4,4-三氟丁-2-炔-1-酮，以及将其用作迈克尔受体以构建芳香族和杂芳香族化合物。
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