Potential of Scenedesmus-fabricated ZnO nanorods in photocatalytic reduction of methylene blue under direct sunlight: kinetics and mechanism.

Organic synthetic dyes are widely used in several industries; however, their inherent resistance to biodegradation necessitates to investigate alternative methods for the remediation of this class of hazardous substances. In the present study, a green synthesis of ZnO nanorods was achieved in a fast, environment-friendly, and safe microwave process employing algal extract. Different metabolites like sugars, proteins, fatty acids, amino acids, and vitamins present in the algal extract reduced the Zn into ZnO. The XRD analysis showed that the nanostructure was a crystalline hexagonal nanorod having a crystalline size of 27.37 nm. The XPS spectra of ZnO nanorod showed characteristic peaks at binding energy 1043, 1020, 496, 137, 87, and 8 eV corresponding to Zn2p, Zn2p, Zn, Zn, Zn, Zn, respectively. The synthesized ZnO nanorods were in-situ functionalized and showed strong catalytic activity in photoreduction of a model organic dye methylene blue (MB) under direct sunlight irradiation. Synthesized ZnO nanorods showed a complete (100%) reduction of model dye MB from its 10 mg/L aqueous solution. The photocatalytic degradation of MB followed the Michaelis-Menten kinetics. The rate of ZnO-catalyzed photocatalytic degradation depends on the concentrations of ZnO, pH, and sunlight irradiation. The ZnO nanorod-catalyzed photoreduction of MB involves hydroxyl radicals. Algal-mediated and microwave-assisted synthesis provides a scalable source of metal oxide nanoparticles for the remediation of dye-containing wastewaters under natural sunlight. Apart from application in the removal of dyes, ZnO nanorods are excellent material for applications in semiconductors, electronics, optics, bio-imaging, and drug delivery.