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氧化钌六氰合铁酸盐作为一种有效的电极修饰剂用于碘酸盐和过氧化氢的安培检测。

Ruthenium Oxide Hexacyanoferrate as an Effective Electrode Modifier for Amperometric Detection of Iodate and Hydrogen Peroxide.

出版信息

Acta Chim Slov. 2020 Dec;67(4):1216-1226.

PMID:33533451
Abstract

Ruthenium oxide hexacyanoferrate (RuOHCF) film was electrochemically deposited on to a glassy carbon (GC) surfaceusing consecutive cyclic voltammetry as a facile and green synthetic strategy. The electrochemical behaviour and electrocatalytic properties of the modified electrode Ru?HCF/GC were evaluated with regards to electroreduction of hydrogen peroxide and iodate in a strong acidic medium (pHs 1.0-2.0) by using different electrochemical techniques, including cyclic voltammetry and amperometry at a constant potential. Electrochemical studies indicated that Ru?HCF/GC possess a high catalytic activity in both studied reactions, fast response and good reproducibility of the current signal. The Ru?HCF/GC exhibits enhanced electrocatalytic behaviour compared with other modified electrodes reported before. The simple and reproducible procedure for electrode fabrication, the wide linear range, anti-interference performance and long-time stability of the Ru?HCF/GC make it a promising sensing material for practical quantitative determination of hydrogen peroxide and iodate. Remarkably, the reported modified.

摘要

氧化钌六氰合铁酸盐(RuOHCF)薄膜通过连续循环伏安法在玻碳(GC)表面电化学沉积,这是一种简单且环保的合成策略。通过使用不同的电化学技术,包括循环伏安法和恒电位安培法,评估了修饰电极 Ru?HCF/GC 在强酸性介质(pH 1.0-2.0)中对过氧化氢和碘酸还原的电化学行为和电催化性能。电化学研究表明,Ru?HCF/GC 在这两种反应中均具有高催化活性、快速响应和良好的电流信号重现性。与之前报道的其他修饰电极相比,Ru?HCF/GC 表现出增强的电催化行为。Ru?HCF/GC 电极制备过程简单、重现性好、线性范围宽、抗干扰性能好、长时间稳定性好,使其成为一种有前途的传感材料,可用于实际定量测定过氧化氢和碘酸。值得注意的是,所报道的修饰

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