滞后价互变异构锰-硝酰基氮氧化物自由基二维框架转变温度的超灵敏压力依赖性
Hypersensitive pressure-dependence of the conversion temperature of hysteretic valence tautomeric manganese-nitronyl nitroxide radical 2D-frameworks.
作者信息
Lecourt Constance, Izumi Yuuta, Maryunina Kseniya, Inoue Katsuya, Bélanger-Desmarais Nicolas, Reber Christian, Desroches Cédric, Luneau Dominique
机构信息
Univ Lyon, Université Claude Bernard Lyon 1, CNRS, Laboratoire des Multimatériaux et Interfaces, F-69622 Villeurbanne, France.
出版信息
Chem Commun (Camb). 2021 Mar 7;57(19):2376-2379. doi: 10.1039/d0cc08144b. Epub 2021 Feb 4.
Valence tautomeric manganese(ii)-radical lamellar compounds {[Mn(NITIm)]X} with NITIm a nitronyl nitroxide radical and X = ClO (1) or BF (2) show a pressure-induced increase of their conversion temperature by approximately 40 K at a mild external pressure of 0.1 GPa, shifting the transition from near room temperature to hot temperature regions.
价态互变异构的锰（II）自由基层状化合物{[Mn（NITIm）]X}，其中NITIm为硝酰基氮氧化物自由基，X = ClO（1）或BF（2），在0.1 GPa的温和外部压力下，其转变温度随压力升高约40 K，使转变从接近室温的区域转移到高温区域。
Zotero 插件