Reduction-oxidation series coupling degradation of chlorophenols in Pd-Catalytic Electro-Fenton system.

Organochlorine pesticides are widespread in soils, sediments and even in groundwater, causing great concern to human health because of its toxicity and carcinogenic effects. The remarkable mineralization and lowered toxicity are particularly important during the removal of organochlorine pesticides. In this study, Pd/CeO was prepared and employed as a bifunctional catalyst, to construct the reduction-oxidation series coupling Electro-Fenton (EF) system. The removal of chlorophenols (CPs) reached over 95% within 10 min at pH 3.0 and a current density of 25 mA/cm in Pd/CeO-EF system. The second-order rate constant of CPs degradation was 10.28 L mmolmin in Pd/CeO-EF system, which was 29 times as fast as the sum of electrolysis with Pd/CeO (0.24 L mmolmin) and EF (0.11 L mmolmin). Dehydrochlorination by Pd [H] contributed to the removal of CPs in Pd/CeO-EF system. The generated reactive oxygen species, mainly OH was also confirmed by ESR to contribute to the removal of CPs. The reduction-oxidation series coupling degradation of CPs in Pd/CeO-EF system increased the TOC removal to 70% in 360 min. The analysis of intermediate products further revealed the reductive and oxidative products in Pd/CeO-EF. Moreover, the system of Pd/CeO-EF exhibited an excellent performance treatment for CPs in actual groundwater. This study provides a new stratagem to eliminate organochlorine pesticides in groundwater environments rapidly and thoroughly.