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双{-四（4--烷基吡啶基）卟啉铈}的合成及其氧化还原开关行为。

Synthesis of Bis{-Tetrakis(4--alkylpyridiniumyl)porphyrinato}cerium and Its Redox Switching Behavior.

机构信息

Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan.

Research Center for Materials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan.

出版信息

Molecules. 2021 Feb 3;26(4):790. doi: 10.3390/molecules26040790.

DOI:10.3390/molecules26040790
PMID:33546465
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7913613/
Abstract

A novel double-decker porphyrin complex, bis{-tetrakis(4--alkylpyridiniumyl)porphyrinato}cerium, was prepared. Electrochemical measurements revealed that this complex exhibited reversible redox waves corresponding to a 1e redox reaction of the cerium center. Treating the complex alternately with an oxidant and a reductant resulted in the reversible redox switching between the oxidized and reduced states in an organic solvent.

摘要

一种新型双层卟啉配合物，双{-四（4--烷基吡啶𬭩基）卟啉基}铈，被制备。电化学测量表明，该配合物表现出对应于铈中心的 1e 氧化还原反应的可逆氧化还原波。用氧化剂和还原剂交替处理该配合物，导致在有机溶剂中在氧化态和还原态之间的可逆氧化还原开关。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b5b/7913613/699dab9d86b3/molecules-26-00790-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b5b/7913613/50f2ef1c4f7f/molecules-26-00790-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b5b/7913613/62eb8f8ab747/molecules-26-00790-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b5b/7913613/b09ac7599d43/molecules-26-00790-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b5b/7913613/b7dfa01b0065/molecules-26-00790-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b5b/7913613/699dab9d86b3/molecules-26-00790-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b5b/7913613/50f2ef1c4f7f/molecules-26-00790-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b5b/7913613/62eb8f8ab747/molecules-26-00790-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b5b/7913613/b09ac7599d43/molecules-26-00790-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b5b/7913613/b7dfa01b0065/molecules-26-00790-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b5b/7913613/699dab9d86b3/molecules-26-00790-g004.jpg

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