Liu Huan-Yu, Yin Yi-Shu, Yang Luo-Ju, Zou Xiao-Ling, Ye Ya-Fang
Acta Chim Slov. 2020 Mar;67(1):130-136.
N'-(3,5-Dichloro-2-hydroxybenzylidene)-4-fluorobenzohydrazide (H2L) was used to prepare oxidovanadium(V) complex [VOL(OEt)(MeOH)] (1) and dioxidomolybdenum(VI) complex [MoO2L(OH2)]·[MoO2L(EtOH)] (2). The complexes were characterized by IR, UV-Vis, NMR spectroscopy, and single crystal X-ray diffraction. X-ray analysis indicates that the complexes are mononuclear species with the metal atoms in octahedral coordination. The complexes were studied for catalytic oxidation property on some olefins with tert-butyl hydroperoxide as oxidant.
N'-(3,5-二氯-2-羟基亚苄基)-4-氟苯甲酰肼（H2L）用于制备氧化钒（V）配合物[VOL(OEt)(MeOH)]（1）和二氧化钼（VI）配合物[MoO2L(OH2)]·[MoO2L(EtOH)]（2）。通过红外光谱、紫外可见光谱、核磁共振光谱和单晶X射线衍射对配合物进行了表征。X射线分析表明，这些配合物是单核物种，金属原子呈八面体配位。研究了这些配合物以叔丁基过氧化氢为氧化剂对一些烯烃的催化氧化性能。
