Pyrolysis Characteristics of Industrial Lignin for Use as a Reductant and an Energy Source for Future Iron Making.

The purpose of this study is to explore the possibility of using industrial lignin instead of pulverized coal as a reducing agent for the production of direct reduced iron (DRI), thus reducing CO emissions. The pyrolysis characteristics and kinetics of pulverized coal and industrial lignin were studied by nonisothermal thermogravimetry. In the three stages of pyrolysis, the weight loss rate of industrial lignin is higher than that of pulverized coal. The volatile matter of industrial lignin is easier to release than that of pulverized coal, but the coking process is longer than that of pulverized coal. The activation energies of pyrolysis of Lu'an anthracite (LA), Shen'mu bituminous coal (SM), alkali lignin (AL), and magnesium lignosulfonate (ML) were 71.10, 70.30, 55.20, and 37.34 kJ·mol at the middle-temperature stage, and 133.64, 98.31, 57.78, and 46.68 kJ·mol at the high-temperature stage, respectively. After pyrolysis, a few nanometer thick carbon film structure appears in alkali lignin coke, which is conducive to the reduction of iron ore powder.