Effect of stretching angle on the stress plateau behavior of main-chain liquid crystal elastomers.

The equilibrium nonlinear stress-stretch relationships for a monodomain main-chain nematic elastomer (MNE) are investigated by varying the angle between the stretching and initial director axes (θ). Angle θ has pronounced effects on the ultimate elongation as well as on the width of the low stress plateau regime (Λ) during director rotation, whereas θ has no appreciable effect on the plateau stress (σ). In the stretching normal to the initial director (θ = 90°), the plateau end exceeds 200% strain. At oblique angles of 90° > θ≥ 35°, Λ decreases with decreasing θ, whereas the definite plateau regime vanishes at θ < 24°. Wide-angle X-ray scattering and polarized optical microscopy measurements reveal that the director rotates uniformly in the biased direction for the MNE of θ°≪ 90°, whereas directors rotating clockwise and counterclockwise are coexistent for θ = 90°. Over the entire plateau regime, the MNEs exhibit pure shear deformation characterized by a Poisson's ratio of zero in the direction of the rotation axis. The Λ for the corresponding polydomain NE (PNE) undergoing a transition to the monodomain alignment is smaller than that of the MNE of θ = 90°, while the σ values for both NEs are almost similar. The semi-soft elasticity concept satisfactorily explains the effects of θ on Λ, and the Λ value of the PNE, using a single anisotropy parameter which is evaluated from the degree of thermally induced deformation of MNEs.