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SnO 量子点//AgVO 纳米带//g-CN 纳米片(0D/1D/2D)三元复合材料的增强太阳能驱动光催化性能用于产氢和染料降解。

Enhanced solar-driven photocatalytic performance of a ternary composite of SnO quantum dots//AgVO nanoribbons//g-CN nanosheets (0D/1D/2D) structures for hydrogen production and dye degradation.

机构信息

Department of Chemical Engineering, Yeungnam University, 214-1, Dae-hakro 280, Gyeongsan, Gyeongbuk, 712-749, South Korea.

Department of Chemical Engineering, King Saud University, P.O. Box 800, Riyadh, 11421, Saudi Arabia.

出版信息

Environ Sci Pollut Res Int. 2021 Jun;28(24):31585-31595. doi: 10.1007/s11356-021-12962-2. Epub 2021 Feb 19.

Abstract

Herein, we report the synthesis of between SnO QDs /AgVO nanoribbons/g-CN nanosheets of ternary photocatalytic systems for the production of H through light irradiation. The SnO/AgVO/g-CN photocatalyst was successfully produced by using the hydrothermal process. The structural characterizations of the samples revealed the successful formation of ternary heterostructures where SnO, AgVO and g-CN (quantum dots/nanoribbons/nanosheets) 0D/1D/2D structures make a good interface with each other. The fabricated heterostructures of AgVO/g-CN and SnO/AgVO/g-CN photocatalytic structures performed enriched photocatalytic performance for H production over that of the pristine g-CN, AgVO and SnO photocatalysts. The AgVO/g-CN and SnO /AgVO/g-CN of photocatalysts were found to produce H of around 17,000 μmol g and 77,000 μmol g, respectively, which is much 4.5 times greater than that of AgVO/g-CN photocatalyst. Moreover, the photodegradation behaviours of prepared catalysts were studied with the dye (rhodamine B, RhB) under light irradiation. The ternary composite SnO/AgVO/g-CN performed photodegradation of RhB in 50 min. The higher photocatalytic activity for the ternary photocatalysts is predominantly due to the effective charge separation at the perfect interface formation amid SnO and AgVO/g-CN.

摘要

在此,我们报告了通过光照射生产 H 的三元光催化体系中 SnO QDs/AgVO 纳米带/g-CN 纳米片的合成。SnO/AgVO/g-CN 光催化剂是通过水热法成功制备的。样品的结构表征表明,成功形成了三元异质结构,其中 SnO、AgVO 和 g-CN(量子点/纳米带/纳米片)0D/1D/2D 结构彼此之间形成了良好的界面。AgVO/g-CN 和 SnO/AgVO/g-CN 光催化结构的构建异质结构表现出比原始 g-CN、AgVO 和 SnO 光催化剂更丰富的 H 生产光催化性能。发现 AgVO/g-CN 和 SnO/AgVO/g-CN 光催化剂分别产生约 17000 μmol g 和 77000 μmol g 的 H,是 AgVO/g-CN 光催化剂的 4.5 倍。此外,还研究了在光照射下用染料(罗丹明 B,RhB)制备催化剂的光降解行为。三元复合 SnO/AgVO/g-CN 在 50 分钟内实现了 RhB 的光降解。三元光催化剂具有更高的光催化活性,主要是由于在 SnO 和 AgVO/g-CN 之间形成完美界面时有效电荷分离。

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