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碳纤维-氧化石墨烯(CF-GO)增强聚合物晶格的立体光刻(SLA)3D打印

Stereolithography (SLA) 3D printing of carbon fiber-graphene oxide (CF-GO) reinforced polymer lattices.

作者信息

Xiao Ran, Ding Mingyang, Wang Yuejiao, Gao Libo, Fan Rong, Lu Yang

机构信息

Department of Mechanical Engineering, City University of Hong Kong, Kowloon, Hong Kong SAR, People's Republic of China.

Nano-Manufacturing Laboratory (NML), Shenzhen Research Institute of City University of Hong Kong, Shenzhen 518057, People's Republic of China.

出版信息

Nanotechnology. 2021 Mar 16;32(23). doi: 10.1088/1361-6528/abe825.

Abstract

Insufficient mechanical properties of stereolithography (SLA)-printed architected polymer metamaterial limits its wide applications such as in the areas of biomedicine and aerospace. One effective solution is to reinforce the structures with micro- or nano- fibers/particles, but their interfaces are critical for the reinforcement. In this work, a carbon fiber-graphene oxide (CF-GO) polymer composite resin and a mild annealing postprocess have been rationally designed and applied into the manufacturing of oct-truss (OCT) lattices.carbon fiber pulling-out experiment was conducted to exhibit the improve effect of GO on the crosslink of the CF and the polymer matrix interface. We found that the maximum reinforcement was realized when the CF-GO (CF: GO is about 3: 1) content is about 0.8 wt%, followed with annealing. Compared with pure polymer lattices, the compression strength of the CF-GO polymer OCT lattices has been significantly increased from ∼0.22 to ∼2.4 MPa, almost 10 times enhancement. Importantly, the compression strength of the CF-GO polymer OCT lattice (3.08 MPa) further increased by ∼30% after optimized annealing. This work suggests an efficient reinforce strategy for SLA-printed metamaterials, and thus can be valuable for advancing various practical applications of mechanical metamaterials.

摘要

立体光刻(SLA)打印的架构聚合物超材料的机械性能不足限制了其在生物医学和航空航天等领域的广泛应用。一种有效的解决方案是用微纤维或纳米纤维/颗粒增强结构,但其界面对于增强效果至关重要。在这项工作中,合理设计了一种碳纤维-氧化石墨烯(CF-GO)聚合物复合树脂和一种温和退火后处理工艺,并将其应用于八面体桁架(OCT)晶格的制造中。进行了碳纤维拔出实验,以展示氧化石墨烯对碳纤维与聚合物基体界面交联的改善作用。我们发现,当CF-GO(CF:GO约为3:1)含量约为0.8 wt%并随后进行退火时,可实现最大增强效果。与纯聚合物晶格相比,CF-GO聚合物OCT晶格的压缩强度从约0.22 MPa显著提高到约2.4 MPa,增强了近10倍。重要的是,经过优化退火后,CF-GO聚合物OCT晶格的压缩强度(3.08 MPa)进一步提高了约30%。这项工作为SLA打印的超材料提出了一种有效的增强策略,因此对于推动机械超材料的各种实际应用具有重要价值。

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