由可异构化配体组成的多孔CuLL'金属有机笼的自分类
Self-sorting of porous CuLL' metal-organic cages composed of isomerisable ligands.
作者信息
Markwell-Heys Adrian W, Schneider Matthew L, Madridejos Jenica Marie L, Metha Gregory F, Bloch Witold M
机构信息
Department of Chemistry, The University of Adelaide, Adelaide 5005, Australia.
出版信息
Chem Commun (Camb). 2021 Mar 18;57(23):2915-2918. doi: 10.1039/d0cc08076d.
PMID:33616581
Abstract
We report the self-sorting of a dynamic combinatorial library (DCL) of metal-organic cages composed of a rotationally isomerisable ligand. Convergence of the DCL occurs upon crystallisation and leads to low-symmetry Cu4L2L'2 cages that display differing porosities based on their overall shape and ligand configuration.
摘要
我们报道了由可旋转异构化配体组成的金属有机笼动态组合库（DCL）的自分类。DCL在结晶时发生收敛，形成低对称性的Cu4L2L'2笼，这些笼根据其整体形状和配体构型表现出不同的孔隙率。
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