Zhang Ying-Ying, Qiu Feng-Yi, Shi Hua-Tian, Yu Weibin
Center for Advanced Materials Research, Henan Key Laboratory of Functional Salt Materials, Zhongyuan University of Technology, Zhengzhou, 450007, P. R. China.
Chem Commun (Camb). 2021 Mar 25;57(24):3010-3013. doi: 10.1039/d0cc08052g. Epub 2021 Feb 24.
Two fascinating triply interlocked [2]catenanes and one simple triangular prism metallacage were constructed by tuning the widths of the organometallic dinuclear building blocks. Notably, the interlocked architectures were disassembled in the presence of large aromatic molecules to form their corresponding monomeric host-guest complexes.
通过调节有机金属双核结构单元的宽度,构建了两个引人入胜的三重互锁[2]索烃和一个简单的三角棱柱金属笼。值得注意的是,在大的芳香分子存在下,互锁结构会解离形成相应的单体主客体配合物。