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海水入侵和重金属污染对沙特阿拉伯红海沿岸地下水水质的影响。

Influence of seawater intrusion and heavy metals contamination on groundwater quality, Red Sea coast, Saudi Arabia.

机构信息

Geology and Geophysics Department, College of Science, King Saud University, Saudi Arabia.

Geology and Geophysics Department, College of Science, King Saud University, Saudi Arabia; Geology Department, Faculty of Science, Zagazig University, Egypt.

出版信息

Mar Pollut Bull. 2021 Apr;165:112094. doi: 10.1016/j.marpolbul.2021.112094. Epub 2021 Feb 24.

Abstract

Groundwater samples were collected from 115 boreholes and dugwells to document the influence of seawater intrusion and heavy metals contamination on groundwater quality of the Al Qunfudhah region along the Red Sea coast, Saudi Arabia. The groundwater quality index (GWQI), metal index (MI), and heavy metal pollution index (HPI) were calculated and multivariate analyses were conducted. pH, EC, TDS, Cl, HCO, SO, NO, NO, PO, SiO, F, NH, Ca, Mg, Na, K, B, Ba, Cd, Cr, As, Ni, Pb, Se, Sb, Hg, Cu, and Zn were analyzed and interpreted. The average values for TDS, Ca, Mg, Na, K, Cl, HCO, SO, B, and Se were greater than the permissible limit of WHO standards for drinking water. Piper plots indicated three types of groundwater facies, Na-K-SO-Cl (72.50%), Ca-Mg-So-Cl (25.50%), and Na-K-CO-HCO (2%). Based on GWQI, MI, and HPI, approximately 37-70% of the groundwater samples fell under poor quality to unsuitable waters (strongly to severely affected), especially in the western part along the Red Sea coast. This proven the role of seawater intrusion through the NE-SW fault system, dissolution/precipitation of carbonates, silicates, fluorite, and gypsum, as well as anthropogenic factors in increasing the concentrations of heavy metals and controlling the chemistry and quality of the groundwater in the study area. These findings provide an important information on heavy metals pollution in coastal aquifer with seawater intrusion along the Red Sea.

摘要

采集了 115 个钻孔和浅井的地下水样本,以记录海水入侵和重金属污染对沙特阿拉伯红海沿岸 Al Qunfudhah 地区地下水质量的影响。计算了地下水质量指数(GWQI)、金属指数(MI)和重金属污染指数(HPI),并进行了多元分析。分析和解释了 pH 值、EC、TDS、Cl、HCO、SO、NO、NO、PO、SiO、F、NH、Ca、Mg、Na、K、B、Ba、Cd、Cr、As、Ni、Pb、Se、Sb、Hg、Cu 和 Zn。TDS、Ca、Mg、Na、K、Cl、HCO、SO、B 和 Se 的平均值大于世界卫生组织饮用水标准的允许限值。Piper 图表明,地下水有三种水相,分别为 Na-K-SO-Cl(72.50%)、Ca-Mg-So-Cl(25.50%)和 Na-K-CO-HCO(2%)。根据 GWQI、MI 和 HPI,大约 37-70%的地下水样本属于劣质到不适宜水(强到严重影响),尤其是在红海沿岸的西部。这证明了海水入侵通过东北-西南断层系统、碳酸盐、硅酸盐、萤石和石膏的溶解/沉淀以及人为因素在增加重金属浓度和控制研究区地下水化学和质量方面的作用。这些发现为红海沿岸受海水入侵影响的沿海含水层重金属污染提供了重要信息。

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