• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

使用μ子自旋弛豫对NASICON结构全固态电池进行原位扩散测量。

In Situ Diffusion Measurements of a NASICON-Structured All-Solid-State Battery Using Muon Spin Relaxation.

作者信息

McClelland Innes, Booth Samuel G, El-Shinawi Hany, Johnston Beth I J, Clough Jasmin, Guo Weimin, Cussen Edmund J, Baker Peter J, Corr Serena A

机构信息

Department of Chemical and Biological Engineering, The University of Sheffield, Sheffield, S1 3JD, U.K.

ISIS Neutron and Muon Source, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Harwell Campus, Didcot, OX11 0QX, U.K.

出版信息

ACS Appl Energy Mater. 2021 Feb 22;4(2):1527-1536. doi: 10.1021/acsaem.0c02722. Epub 2021 Jan 21.

DOI:10.1021/acsaem.0c02722
PMID:33644700
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7903674/
Abstract

In situ muon spin relaxation is demonstrated as an emerging technique that can provide a volume-averaged local probe of the ionic diffusion processes occurring within electrochemical energy storage devices as a function of state of charge. Herein, we present work on the conceptually interesting NASICON-type all-solid-state battery LiM(PO), using M = Ti in the cathode, M = Zr in the electrolyte, and a Li metal anode. The pristine materials are studied individually and found to possess low ionic hopping activation energies of ∼50-60 meV and competitive Li self-diffusion coefficients of ∼10-10 cm s at 336 K. Lattice matching of the cathode and electrolyte crystal structures is employed for the all-solid-state battery to enhance Li diffusion between the components in an attempt to minimize interfacial resistance. The cell is examined by in situ muon spin relaxation, providing the first example of such ionic diffusion measurements. This technique presents an opportunity to the materials community to observe intrinsic ionic dynamics and electrochemical behavior simultaneously in a nondestructive manner.

摘要

原位μ子自旋弛豫被证明是一种新兴技术，它可以作为一种体积平均的局部探针，用于探测电化学储能装置中随充电状态变化而发生的离子扩散过程。在此，我们展示了关于概念上有趣的NASICON型全固态电池LiM(PO)的研究工作，其中阴极中的M = Ti，电解质中的M = Zr，以及锂金属阳极。对原始材料进行了单独研究，发现它们在336 K时具有约50 - 60 meV的低离子跳跃活化能和约10⁻¹⁰ cm² s⁻¹的竞争性锂自扩散系数。全固态电池采用阴极和电解质晶体结构的晶格匹配，以增强各组件之间的锂扩散，试图最小化界面电阻。通过原位μ子自旋弛豫对电池进行了检测，提供了此类离子扩散测量的首个实例。该技术为材料学界提供了一个以非破坏性方式同时观察本征离子动力学和电化学行为的机会。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/477338d0549d/ae0c02722_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/838931c60b7a/ae0c02722_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/4f8309bba543/ae0c02722_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/b4825ed823ec/ae0c02722_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/60a6fd136531/ae0c02722_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/83bd315d9e9b/ae0c02722_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/8558b97d6d28/ae0c02722_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/0e242df6d062/ae0c02722_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/477338d0549d/ae0c02722_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/838931c60b7a/ae0c02722_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/4f8309bba543/ae0c02722_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/b4825ed823ec/ae0c02722_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/60a6fd136531/ae0c02722_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/83bd315d9e9b/ae0c02722_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/8558b97d6d28/ae0c02722_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/0e242df6d062/ae0c02722_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b2ba/7903674/477338d0549d/ae0c02722_0008.jpg

相似文献

1
In Situ Diffusion Measurements of a NASICON-Structured All-Solid-State Battery Using Muon Spin Relaxation.使用μ子自旋弛豫对NASICON结构全固态电池进行原位扩散测量。
ACS Appl Energy Mater. 2021 Feb 22;4(2):1527-1536. doi: 10.1021/acsaem.0c02722. Epub 2021 Jan 21.
2
Graphene Regulated Ceramic Electrolyte for Solid-State Sodium Metal Battery with Superior Electrochemical Stability.用于固态钠金属电池的具有优异电化学稳定性的石墨烯调控陶瓷电解质。
ACS Appl Mater Interfaces. 2019 Feb 6;11(5):5064-5072. doi: 10.1021/acsami.8b19519. Epub 2019 Jan 24.
3
In situ electrochemical modification of the Li/LiAlTi(PO) interface in solid lithium metal batteries via an electrolyte additive.通过电解质添加剂对固态锂金属电池中Li/LiAlTi(PO)界面进行原位电化学改性。
J Colloid Interface Sci. 2023 Jul;641:396-403. doi: 10.1016/j.jcis.2023.03.069. Epub 2023 Mar 13.
4
Effect of a layer-by-layer assembled ultra-thin film on the solid electrolyte and Li interface.逐层组装超薄膜对固体电解质和锂界面的影响。
Nanoscale Adv. 2022 Sep 14;4(21):4606-4616. doi: 10.1039/d2na00521b. eCollection 2022 Oct 25.
5
Electrode-Electrolyte Interfaces in Lithium-Sulfur Batteries with Liquid or Inorganic Solid Electrolytes.液体或无机固体电解质的锂硫电池的电极-电解质界面。
Acc Chem Res. 2017 Nov 21;50(11):2653-2660. doi: 10.1021/acs.accounts.7b00460. Epub 2017 Nov 7.
6
Matchmaker of Marriage between a Li Metal Anode and NASICON-Structured Solid-State Electrolyte: Plastic Crystal Electrolyte and Three-Dimensional Host Structure.锂金属阳极与NASICON结构固态电解质之间的“婚姻”媒人：塑性晶体电解质与三维主体结构
ACS Appl Mater Interfaces. 2020 Oct 7;12(40):44754-44761. doi: 10.1021/acsami.0c12962. Epub 2020 Sep 25.
7
The Li-ion rechargeable battery: a perspective.锂离子可充电电池：一个展望。
J Am Chem Soc. 2013 Jan 30;135(4):1167-76. doi: 10.1021/ja3091438. Epub 2013 Jan 18.
8
Insight into Ion Diffusion Dynamics/Mechanisms and Electronic Structure of Highly Conductive Sodium-Rich NaLaZrSiPO (0 ≤ ≤ 0.5) Solid-State Electrolytes.深入了解高导电性富钠NaLaZrSiPO (0 ≤ ≤ 0.5) 固态电解质的离子扩散动力学/机制及电子结构。
ACS Appl Mater Interfaces. 2021 Mar 24;13(11):13132-13138. doi: 10.1021/acsami.0c21882. Epub 2021 Mar 15.
9
Li-Ion Diffusion in Nanoconfined LiBH-LiI/AlO: From 2D Bulk Transport to 3D Long-Range Interfacial Dynamics.锂离子在纳米受限LiBH-LiI/AlO中的扩散：从二维体相传输到三维长程界面动力学
ACS Appl Mater Interfaces. 2020 Aug 26;12(34):38570-38583. doi: 10.1021/acsami.0c10361. Epub 2020 Aug 13.
10
Rhombohedral LiYZr(PO) Solid Electrolyte Prepared by Hot-Pressing for All-Solid-State Li-Metal Batteries.通过热压法制备的用于全固态锂金属电池的菱面体LiYZr(PO)固体电解质。
Materials (Basel). 2020 Apr 6;13(7):1719. doi: 10.3390/ma13071719.

引用本文的文献

1
Na Diffusion in Hard Carbon Studied with Positive Muon Spin Rotation and Relaxation.用正μ子自旋旋转和弛豫研究硬碳中的钠扩散
ACS Phys Chem Au. 2021 Nov 15;2(2):98-107. doi: 10.1021/acsphyschemau.1c00036. eCollection 2022 Mar 23.

本文引用的文献

1
Challenges and perspectives of NASICON-type solid electrolytes for all-solid-state lithium batteries.NASICON 型固体电解质在全固态锂电池中的挑战与展望。
Nanotechnology. 2020 Mar 27;31(13):132003. doi: 10.1088/1361-6528/ab5be7. Epub 2019 Nov 26.
2
Evaluating lithium diffusion mechanisms in the complex spinel LiNiGeO.评估复杂尖晶石 LiNiGeO 中的锂扩散机制。
Phys Chem Chem Phys. 2019 Oct 24;21(41):23111-23118. doi: 10.1039/c9cp02907a.
3
Dendrite nucleation in lithium-conductive ceramics.锂导电陶瓷中的枝晶成核。
Phys Chem Chem Phys. 2019 Sep 18;21(36):20354-20359. doi: 10.1039/c9cp03884a.
4
Fundamentals of inorganic solid-state electrolytes for batteries.用于电池的无机固态电解质基础
Nat Mater. 2019 Dec;18(12):1278-1291. doi: 10.1038/s41563-019-0431-3. Epub 2019 Aug 19.
5
Enhancing High-Voltage Performance of Ni-Rich Cathode by Surface Modification of Self-Assembled NASICON Fast Ionic Conductor LiZr(PO).通过自组装NASICON快离子导体LiZr(PO)的表面改性提高富镍阴极的高压性能
ACS Appl Mater Interfaces. 2019 May 1;11(17):15507-15516. doi: 10.1021/acsami.9b00389. Epub 2019 Apr 22.
6
NaLaTeO: Na conduction in a novel Na-rich double perovskite.新型富钠双钙钛矿中的钠离子传导
Chem Commun (Camb). 2018 Sep 6;54(72):10040-10043. doi: 10.1039/c8cc03367f.
7
Mechanistic insights of Li diffusion within doped LiFePO from Muon Spectroscopy.利用μ子光谱学对掺杂LiFePO₄中锂扩散的机理洞察
Sci Rep. 2018 Mar 7;8(1):4114. doi: 10.1038/s41598-018-22435-1.
8
Promises, Challenges, and Recent Progress of Inorganic Solid-State Electrolytes for All-Solid-State Lithium Batteries.全固态锂电池用无机固体电解质的承诺、挑战与最新进展。
Adv Mater. 2018 Apr;30(17):e1705702. doi: 10.1002/adma.201705702. Epub 2018 Feb 22.
9
Interfacial Chemistry in Solid-State Batteries: Formation of Interphase and Its Consequences.固态电池中的界面化学：中间相的形成及其影响。
J Am Chem Soc. 2018 Jan 10;140(1):250-257. doi: 10.1021/jacs.7b09531. Epub 2017 Dec 28.
10
Li-ion diffusion in Li intercalated graphite CLi and CLi probed by μSR.通过μSR探测锂嵌入石墨CLi和CLi中的锂离子扩散。
Phys Chem Chem Phys. 2017 Jul 26;19(29):19058-19066. doi: 10.1039/c7cp02047c.