Guo Jialing, Nie Yunhuan, Xu Ning
Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Microscale Magnetic Resonance and Department of Physics, University of Science and Technology of China, Hefei 230026, People's Republic of China.
Soft Matter. 2021 Mar 28;17(12):3397-3403. doi: 10.1039/d0sm02199g. Epub 2021 Mar 1.
Recent studies have shown that the melting of two-dimensional crystals can be either continuous or discontinuous, relying on multiple parameters such as particle stiffness, density, and particle size dispersity. However, what determines the continuity or discontinuity of the two-dimensional melting remains elusive. Here we study the two-dimensional melting of binary mixtures of soft-core particles. The two particle species are different in either particle size or particle stiffness. Starting with the mono-component systems which exhibit discontinuous hexatic-liquid transition, we gradually increase the particle size or stiffness dispersity and find that the hexatic-liquid coexistent region shrinks and eventually vanishes above a critical dispersity. Therefore, the growth of disorder caused by the particle size or stiffness dispersity leads to the discontinuous-continuous transition of the two-dimensional melting. We further find that as long as the melting is continuous the defect concentrations on the boundary between hexatic and liquid phases remain almost constant, accompanied by an almost constant correlation length. These characteristic defect concentrations and correlation length are universal and independent of particle interactions, temperature, and type of particle dispersity, which act as signatures of the continuous two-dimensional melting.
最近的研究表明,二维晶体的熔化可以是连续的,也可以是不连续的,这取决于多个参数,如粒子刚度、密度和粒径分散度。然而,决定二维熔化连续性或不连续性的因素仍然难以捉摸。在这里,我们研究了软核粒子二元混合物的二维熔化。这两种粒子在粒径或粒子刚度上有所不同。从表现出不连续六方相-液相转变的单组分系统开始,我们逐渐增加粒径或刚度分散度,发现六方相-液相共存区域缩小,最终在临界分散度以上消失。因此,由粒径或刚度分散度引起的无序增长导致了二维熔化的不连续-连续转变。我们进一步发现,只要熔化是连续的,六方相和液相之间边界上的缺陷浓度就几乎保持不变,同时相关长度也几乎保持不变。这些特征性的缺陷浓度和相关长度是普遍的,并且与粒子相互作用、温度和粒子分散类型无关,它们是连续二维熔化的标志。