Graduate School of Water Resources, Sungkyunkwan University (SKKU), 2066, Seobu-ro, Jangan-gu, Suwon, Gyeonggi-do, 16419, Republic of Korea.
Graduate School of Water Resources, Sungkyunkwan University (SKKU), 2066, Seobu-ro, Jangan-gu, Suwon, Gyeonggi-do, 16419, Republic of Korea.
Chemosphere. 2021 Jul;275:130047. doi: 10.1016/j.chemosphere.2021.130047. Epub 2021 Feb 22.
Monitoring fouling behavior for better understanding and control has recently gained increasing attention. However, there is no practical method for observing membrane fouling in real time, especially in the forward osmosis (FO) process. In this article, we used the optical coherence tomography (OCT) technique to conduct real-time monitoring of the membrane fouling layer in the FO process. Fouling tendency of the FO membrane was observed at four distinguished stages for 21 days using a regular membrane cleaning method. In this method, chemical cleaning, which extracts two to three times as much organic matter (OM) as physical cleaning, was used as an effective method. Real-time OCT image observations indicated that a thin, dense, and flat fouling layer was formed (initial stage). On the other hand, a fouling layer with a thick and rough surface was formed later (final stage). A deep learning convolutional neural network model was developed to predict membrane fouling characteristics based on a dataset of real-time fouling images. The model results show a very high correlation between the predicted data and the actual data. R equals 0.90, 0.86, 0.92, and 0.90 for the thickness, porosity, roughness, and density of the fouling layer, respectively. As a promising approach, real-time monitoring of fouling layers on the surface of FO membranes and the prediction of fouling layer characteristics using deep learning models can characterize and control membrane fouling in FO and other membrane processes.
近年来,人们越来越关注通过监测污垢行为来更好地理解和控制污垢。然而,目前还没有实用的方法可以实时观察膜污染,特别是在正向渗透(FO)过程中。在本文中,我们使用光学相干断层扫描(OCT)技术对 FO 过程中的膜污染层进行实时监测。使用常规的膜清洗方法,在 21 天的时间里,我们在四个不同的阶段观察了 FO 膜的污垢倾向。在这种方法中,化学清洗(提取的有机物(OM)比物理清洗多两到三倍)被用作一种有效的方法。实时 OCT 图像观察表明,形成了一层薄、密、平整的污垢层(初始阶段)。另一方面,后来形成了一层厚而粗糙的污垢层(最终阶段)。我们开发了一种基于实时污垢图像数据集的深度学习卷积神经网络模型,以预测膜污染特性。模型结果表明,预测数据与实际数据之间具有非常高的相关性。对于污垢层的厚度、孔隙率、粗糙度和密度,R 分别为 0.90、0.86、0.92 和 0.90。作为一种很有前途的方法,使用深度学习模型对 FO 膜表面污垢层进行实时监测以及预测污垢层特性,可以对 FO 和其他膜过程中的膜污染进行特征化和控制。