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聚丙烯非织造土工布的紫外线效应及热分析研究

Study of the Ultraviolet Effect and Thermal Analysis on Polypropylene Nonwoven Geotextile.

作者信息

Valentin Clever Aparecido, Kobelnik Marcelo, Franco Yara Barbosa, Lavoie Fernando Luiz, Silva Jefferson Lins da, Luz Marta Pereira da

机构信息

São Carlos School of Engineering, University of São Paulo-USP, São Paulo 13566-590, Brazil.

Department of Civil Engineering, Mauá Institute of Technology, São Caetano do Sul 09580-900, Brazil.

出版信息

Materials (Basel). 2021 Feb 26;14(5):1080. doi: 10.3390/ma14051080.

Abstract

The use of polymeric materials such as geosynthetics in infrastructure works has been increasing over the last decades, as they bring down costs and provide long-term benefits. However, the aging of polymers raises the question of its long-term durability and for this reason researchers have been studying a sort of techniques to search for the required renewal time. This paper examined a commercial polypropylene (PP) nonwoven geotextile before and after 500 h and 1000 h exposure to ultraviolet (UV) light by performing laboratory accelerated ultraviolet-aging tests. The state of the polymeric material after UV exposure was studied through a wide set of tests, including mechanical and physical tests and thermoanalytical tests and scanning electron microscopy analysis. The calorimetric evaluations (DSC) showed distinct behaviors in sample melting points, attributed to the UV radiation effect on the aged samples. Furthermore, after exposure, the samples presented low thermal stability in the thermomechanical analysis (TMA), with a continuing decrease in their thicknesses. The tensile tests showed an increase in material stiffness after exposition. This study demonstrates that UV aging has effects on the properties of the polypropylene polymer.

摘要

在过去几十年里,土工合成材料等聚合材料在基础设施工程中的应用一直在增加,因为它们能降低成本并带来长期效益。然而,聚合物的老化引发了其长期耐久性的问题,因此研究人员一直在研究各种技术来寻找所需的更新时间。本文通过进行实验室加速紫外线老化试验,对一种商用聚丙烯(PP)非织造土工布在暴露于紫外线(UV)光500小时和1000小时前后进行了检测。通过一系列广泛的测试,包括力学和物理测试、热分析测试以及扫描电子显微镜分析,研究了紫外线暴露后聚合材料的状态。量热评估(DSC)显示出老化样品熔点的明显变化,这归因于紫外线辐射对老化样品的影响。此外,暴露后,样品在热机械分析(TMA)中表现出低热稳定性,其厚度持续减小。拉伸试验表明暴露后材料刚度增加。这项研究表明紫外线老化对聚丙烯聚合物的性能有影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/abb4/7956639/4698d6b5fb9d/materials-14-01080-g001.jpg

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