Fayyaz Osama, Khan Adnan, Shakoor R A, Hasan Anwarul, Yusuf Moinuddin M, Montemor M F, Rasul Shahid, Khan Kashif, Faruque M R I, Okonkwo Paul C
Center for Advanced Materials (CAM), Qatar University, 2713, Doha, Qatar.
Department of Mechanical and Industrial Engineering, College of Engineering, Qatar University, 2713, Doha, Qatar.
Sci Rep. 2021 Mar 5;11(1):5327. doi: 10.1038/s41598-021-84716-6.
In the present study, the effect of concentration of titanium carbide (TiC) particles on the structural, mechanical, and electrochemical properties of Ni-P composite coatings was investigated. Various amounts of TiC particles (0, 0.5, 1.0, 1.5, and 2.0 g L) were co-electrodeposited in the Ni-P matrix under optimized conditions and then characterized by employing various techniques. The structural analysis of prepared coatings indicates uniform, compact, and nodular structured coatings without any noticeable defects. Vickers microhardness and nanoindentation results demonstrate the increase in the hardness with an increasing amount of TiC particles attaining its terminal value (593HV) at the concentration of 1.5 g L. Further increase in the concentration of TiC particles results in a decrease in hardness, which can be ascribed to their accumulation in the Ni-P matrix. The electrochemical results indicate the improvement in corrosion protection efficiency of coatings with an increasing amount of TiC particles reaching to ~ 92% at 2.0 g L, which can be ascribed to a reduction in the active area of the Ni-P matrix by the presence of inactive ceramic particles. The favorable structural, mechanical, and corrosion protection characteristics of Ni-P-TiC composite coatings suggest their potential applications in many industrial applications.
在本研究中,研究了碳化钛(TiC)颗粒浓度对Ni-P复合涂层的结构、力学和电化学性能的影响。在优化条件下,将不同量的TiC颗粒(0、0.5、1.0、1.5和2.0 g/L)共电沉积在Ni-P基体中,然后采用各种技术对其进行表征。对制备涂层的结构分析表明,涂层结构均匀、致密且呈结节状,无明显缺陷。维氏显微硬度和纳米压痕结果表明,随着TiC颗粒量的增加,硬度增加,在1.5 g/L的浓度下达到终值(593HV)。TiC颗粒浓度的进一步增加导致硬度降低,这可归因于它们在Ni-P基体中的聚集。电化学结果表明,随着TiC颗粒量的增加,涂层的耐腐蚀效率提高,在2.0 g/L时达到约92%,这可归因于惰性陶瓷颗粒的存在使Ni-P基体的活性面积减小。Ni-P-TiC复合涂层良好的结构、力学和耐腐蚀特性表明它们在许多工业应用中具有潜在应用价值。