• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

新型4-苄氧基苯基4-[4-(正十二烷氧基)苯甲酰氧基]苯甲酸酯液晶的合成与表征

Synthesis and characterization of novel 4-benzyloxyphenyl 4-[4-(n-dodecyloxy)benzoyloxy]benzoate liquid crystal.

作者信息

Balkanli Emine, Çakar Fatih, Ocak Hale, Cankurtaran Özlem, Bİlgİn Eran Belkız

机构信息

Department of Chemistry, Faculty of Arts and Science, Yıldız Technical University, İstanbul Turkey.

出版信息

Turk J Chem. 2021 Feb 17;45(1):71-81. doi: 10.3906/kim-2007-64. eCollection 2021.

DOI:10.3906/kim-2007-64
PMID:33679154
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7925317/
Abstract

Liquid crystal (LC) compound 4-Benzyloxyphenyl 4-[4-( -dodecyloxy)benzoyloxy]benzoate (BDBB) was prepared and characterized. Inverse gas chromatography (IGC) was to be a beneficial analysis method for the research of thermodynamic characteristics of the new LC. Acetate and alcohol isomers were used to examine LC selectivity via the IGC technique at temperatures between 333.2 K and 483.2 K. The retention diagrams of -heptane, -octane, -nonane, -decane, undecane, dodecane, tridecane, -butyl acetate, isobutyl acetate, ethyl acetate, -propylbenzene, isopropylbenzene, ethylbenzene, chlorobenzene, and toluene on BDBB were plotted with temperatures of 483.2-493.2 K. Flory-Huggins interaction parameter and weight fraction activity coefficient at infinite dilution were researched for BDBB.

摘要

制备并表征了液晶（LC）化合物4-苄氧基苯基4-[4-( -十二烷氧基)苯甲酰氧基]苯甲酸酯（BDBB）。反相气相色谱法（IGC）是研究新型液晶热力学特性的一种有益分析方法。在333.2 K至483.2 K的温度范围内，通过IGC技术使用乙酸酯和醇异构体来检测液晶的选择性。绘制了483.2 - 493.2 K温度下庚烷、辛烷、壬烷、癸烷、十一烷、十二烷、十三烷、乙酸丁酯、乙酸异丁酯、乙酸乙酯、丙苯、异丙苯、乙苯、氯苯和甲苯在BDBB上的保留图。研究了BDBB的弗洛里-哈金斯相互作用参数和无限稀释下的重量分数活度系数。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/c5b3b3eb89d6/turkjchem-45-71-fig007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/461f57127b32/turkjchem-45-71-fig001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/4ba0d82957f3/turkjchem-45-71-fig002a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/e1e4208b8310/turkjchem-45-71-fig003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/737baabe4f7f/turkjchem-45-71-fig004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/8e43b16640df/turkjchem-45-71-fig005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/697e73956328/turkjchem-45-71-fig006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/c5b3b3eb89d6/turkjchem-45-71-fig007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/461f57127b32/turkjchem-45-71-fig001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/4ba0d82957f3/turkjchem-45-71-fig002a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/e1e4208b8310/turkjchem-45-71-fig003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/737baabe4f7f/turkjchem-45-71-fig004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/8e43b16640df/turkjchem-45-71-fig005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/697e73956328/turkjchem-45-71-fig006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8d28/7925317/c5b3b3eb89d6/turkjchem-45-71-fig007.jpg

相似文献

1
Synthesis and characterization of novel 4-benzyloxyphenyl 4-[4-(n-dodecyloxy)benzoyloxy]benzoate liquid crystal.新型4-苄氧基苯基4-[4-(正十二烷氧基)苯甲酰氧基]苯甲酸酯液晶的合成与表征
Turk J Chem. 2021 Feb 17;45(1):71-81. doi: 10.3906/kim-2007-64. eCollection 2021.
2
Determination of thermodynamic properties of isotactic poly(1-butene) at infinite dilution using density and inverse gas chromatography.使用密度法和反相气相色谱法测定全同立构聚（1-丁烯）在无限稀释时的热力学性质。
J Chromatogr A. 2005 Mar 18;1068(2):297-305. doi: 10.1016/j.chroma.2005.01.090.
3
Determination of thermodynamic properties of poly (cyclohexyl methacrylate) by inverse gas chromatography.用反相气相色谱法测定聚（甲基丙烯酸环己酯）的热力学性质
Se Pu. 2014 Jul;32(7):746-52. doi: 10.3724/sp.j.1123.2014.04028.
4
[Determination of solubility parameters of high density polyethylene by inverse gas chromatography].
Se Pu. 2011 Nov;29(11):1118-21.
5
Determination of the thermodynamic parameters of ionic liquid 1-hexyl-3-methylimidazolium tetrafluoroborate by inverse gas chromatography.通过反相气相色谱法测定离子液体1-己基-3-甲基咪唑四氟硼酸盐的热力学参数
Se Pu. 2015 Jan;33(1):58-64. doi: 10.3724/sp.j.1123.2014.09018.
6
Determination of the solubility parameter of ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate by inverse gas chromatography.通过反相气相色谱法测定离子液体1-丁基-3-甲基咪唑四氟硼酸盐的溶解度参数
Se Pu. 2015 Nov;33(11):1192-8. doi: 10.3724/sp.j.1123.2015.04041.
7
[Determination of the solubility parameter of organosolv lignin by inverse gas chromatography].
Se Pu. 2013 Feb;31(2):143-6. doi: 10.3724/sp.j.1123.2012.09024.
8
[Determination of solubility parameter for dicationic ionic liquid by inverse gas chromatography].[用反相气相色谱法测定双阳离子离子液体的溶解度参数]
Se Pu. 2009 Jul;27(4):480-3.
9
[Determination of solubility parameters for asymmetrical dicationic ionic liquids by inverse gas chromatography].[通过反相气相色谱法测定不对称双阳离子离子液体的溶解度参数]
Se Pu. 2015 Dec;33(12):1301-6. doi: 10.3724/sp.j.1123.2015.07030.
10
Thermodynamic properties of hyperbranched polymer, Boltorn U3000, using inverse gas chromatography.使用反气相色谱法研究超支化聚合物 Boltorn U3000 的热力学性质。
J Phys Chem B. 2009 Nov 19;113(46):15312-21. doi: 10.1021/jp905949g.

引用本文的文献

1
Application of inverse gas chromatography in the surface characterization of diethanol amine modified polystyrene based polymer.反相气相色谱法在二乙醇胺改性聚苯乙烯基聚合物表面表征中的应用
Turk J Chem. 2021 Oct 19;45(5):1533-1542. doi: 10.3906/kim-2105-45. eCollection 2021.

本文引用的文献

1
Twist grain boundary (TGB) states of chiral liquid crystalline bent-core mesogens.
Chem Commun (Camb). 2015 May 1;51(35):7512-5. doi: 10.1039/c5cc01592h.
2
Inverse gas chromatography as a source of physiochemical data.反相气相色谱法作为物理化学数据的来源。
J Chromatogr A. 2009 Mar 6;1216(10):1551-66. doi: 10.1016/j.chroma.2008.10.096. Epub 2008 Nov 5.