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基于生物质转化的乙酰丙酸工厂在技术经济和㶲分析下的技术评估

Technical Evaluation of a Levulinic Acid Plant Based on Biomass Transformation under Techno-Economic and Exergy Analyses.

作者信息

Meramo Hurtado Samir Isaac, Puello Plinio, Cabarcas Amaury

机构信息

Samir I. Meramo-Hurtado, Research Group on Information Technology, Modeling, and Simulation (GITEMOS), Systems Engineering Program, Universidad de Cartagena, 30th Street #39b-192, 130001 Cartagena, Colombia.

Plinio Puello, Research Group on Information Technology, Modeling, and Simulation (GITEMOS), Systems Engineering Program, Universidad de Cartagena, 30th Street #39b-192, 130001 Cartagena, Colombia.

出版信息

ACS Omega. 2021 Feb 17;6(8):5627-5641. doi: 10.1021/acsomega.0c06088. eCollection 2021 Mar 2.

Abstract

Levulinic acid (LA) recently has attracted much attention as a promising biorefinery platform due to its potential to be economical and sustainable. This paper addresses technical, techno-economic, and exergetic analyses of an industrial LA production via acid-catalyzed dehydration. The process was simulated through Aspen Plus, considering a processing capacity of 15,175.60 kg/h of banana empty fruit bunches. The global productivity yield was 25.56%, producing 3883.13 kg/h of LA. The techno-economic analysis evidenced that this process may be an attractive alternative for biomass valorization, considering the obtained financial results. This process's total production cost was 0.178 $USD per kilogram of biomass and a total annualized cost of $USD 29,163,638.95. Exergy analysis revealed that this process had an irreversibility rate of 1.48 × 10 MJ/h. The pretreatment stage presented the lowest exergetic efficiency. Globally, the exergy efficiency was 53.76%, which is within the reported results for analogous biomass transformation processes.

摘要

由于具有经济和可持续的潜力,乙酰丙酸(LA)最近作为一个有前景的生物炼制平台备受关注。本文对通过酸催化脱水进行工业LA生产进行了技术、技术经济和火用分析。该过程通过Aspen Plus进行模拟,考虑香蕉空果串的处理能力为15,175.60 kg/h。全球生产率为25.56%,每小时生产3883.13 kg的LA。技术经济分析表明,考虑到所获得的财务结果,该过程可能是生物质增值的一个有吸引力的替代方案。该过程的总生产成本为每千克生物质0.178美元,总年化成本为29,163,638.95美元。火用分析表明,该过程的不可逆率为1.48×10 MJ/h。预处理阶段的火用效率最低。总体而言,火用效率为53.76%,这在类似生物质转化过程的报告结果范围内。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1e06/7931420/179e58a4fb28/ao0c06088_0002.jpg

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