A sensitive turn-off-on fluorometric sensor based on S,N co-doped carbon dots for environmental analysis of Hg(II) ion.

A simple and sensitive fluorescence turn-off-on sensor was established by means of S,N co-doped carbon dots (S,N-CDs) and Ag nanoparticles (AgNPs) for the determination of Hg . For this purpose, blue emissive S,N-CDs were hydrothermally synthesized and characterized using transmission electron microscopy, Fourier transform infrared spectroscopy, and energy dispersive X-ray spectroscopy. We observed that the fluorescence intensity of the as-prepared S,N-CDs was impressively quenched by AgNPs. The quenching mechanism was studied and attributed to nanosurface energy transfer and the inner filter effect between S,N-CDs and AgNPs. Furthermore, by adding Hg , the fluorescence intensity of S,N-CDs/AgNPs was restored as a result of aggregation of AgNPs in the presence of Hg . Based on these facts, S,N-CDs and AgNPs were exploited to design a sensitive turn-off-on sensor for analysis of Hg . The recovered fluorescence signal was proportional to the concentration of Hg in the range 1.5-2000 nM with a detection limit of 0.51 nM. The established sensor was used with satisfactory results for measurement of Hg in environmental water samples.