在北极向上和南极向上的法拉第几何条件下，Pt OEP和F -ppyPt (acac) 的磁圆偏振发光。
Magnetic Circularly Polarized Luminescence from Pt OEP and F -ppyPt (acac) under North-up and South-up Faraday Geometries.
作者信息
Matsudaira Kana, Mimura Yuki, Hotei Junichi, Yagi Shigeyuki, Yamashita Ken-Ichi, Fujiki Michiya, Imai Yoshitane
机构信息
Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, 3-4-1 Kowakae, Higashi-Osaka, Osaka, 577-8502, Japan.
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka, 599-8531, Japan.
出版信息
Chem Asian J. 2021 Apr 19;16(8):926-930. doi: 10.1002/asia.202100172. Epub 2021 Mar 23.
The magnetic circularly polarized luminescence (MCPL) and photoluminescence (PL) spectra of achiral (2,3,7,8,12,13,17,18-octaethylporphyrinato)platinum(II), PtOEP, and [2-(4',6'-difluorophenyl)pyridinato-N,C ]platinum(II) acetylacetonate-O,O, F -ppyPt(acac), in toluene and dichloromethane solutions were recorded under an external magnetic field of 1.6 T with N-up and S-up Faraday geometries. The MCPL signs of PtOEP and F -ppyPt(acac) were controlled solely by changing the N-up and S-up geometries. The MCPL/PL wavelengths of F -ppyPt(acac) in solutions were varied by the ratio of the monomeric and excimeric species.
在手性（2,3,7,8,12,13,17,18-八乙基卟啉）铂（II）（PtOEP）和[2-（4'，6'-二氟苯基）吡啶-N，C]铂（II）乙酰丙酮盐-O，O（F-ppyPt(acac)）的甲苯和二氯甲烷溶液中，在1.6 T的外部磁场下，采用N朝上和S朝上的法拉第几何结构记录了磁圆偏振发光（MCPL）和光致发光（PL）光谱。通过改变N朝上和S朝上的几何结构，可单独控制PtOEP和F-ppyPt(acac)的MCPL符号。溶液中F-ppyPt(acac)的MCPL/PL波长会因单体和准分子种类的比例而变化。
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