Wang Xiaoju, Chen Xi, Xu Guobin, Li Jie, Guo Jiaqi, Wang Qi
Appl Opt. 2021 Mar 10;60(8):2304-2313. doi: 10.1364/AO.416896.
Fluorescent anti-counterfeiting is one of the most widely used anti-counterfeiting technologies at present. The demand to develop new anti-counterfeiting materials and technology is more and more urgent. Zinc oxide quantum dots (ZnO QDs) have superior fluorescent properties under ultraviolet light, making them a suitable replacement for traditional phosphors for anti-counterfeiting printing, which is environmentally friendly and meets the needs of sustainable development. In this paper, water-soluble ZnO QDs with an average particle size of 5.64 nm were prepared. Paper coated by ZnO QDs was obtained after ultrasonic treatment, which could emit bright yellow fluorescence when excited by ultraviolet light. As the concentration of ultrasonic solution is increased, the loading amount of ZnO QDs on the coated paper increased gradually, reaching the maximum when the concentration is increased to 1, which then does not change with an increase in concentration. The fluorescent intensity of the coated paper was consistent with the changing trend of the loading amount. The coated paper has excellent optical stability, is easy to recycle, and provides simple identification of authenticity by ultraviolet light and anti-copy functionality. Their application in packaging and printing is of great significance to the development of complex, concealed and non-repeatable anti-counterfeiting technology.
荧光防伪是目前应用最为广泛的防伪技术之一。开发新型防伪材料和技术的需求日益迫切。氧化锌量子点(ZnO QDs)在紫外光下具有优异的荧光性能,使其成为传统防伪印刷磷光体的合适替代品,既环保又符合可持续发展的需求。本文制备了平均粒径为5.64 nm的水溶性ZnO QDs。经超声处理后得到涂覆有ZnO QDs的纸张,在紫外光激发下能发出亮黄色荧光。随着超声溶液浓度的增加,涂覆纸上ZnO QDs的负载量逐渐增加,当浓度增加到1时达到最大值,之后不再随浓度增加而变化。涂覆纸的荧光强度与负载量的变化趋势一致。涂覆纸具有优异的光学稳定性,易于回收利用,通过紫外光可实现简单的真伪鉴定和防复印功能。它们在包装和印刷中的应用对复杂、隐蔽和不可重复的防伪技术的发展具有重要意义。