Zhang Shuai, Saji Sandra Elizabeth, Yin Zongyou, Zhang Hongbo, Du Yaping, Yan Chun-Hua
Tianjin Key Lab for Rare Earth Materials and Applications, Center for Rare Earth and Inorganic Functional Materials, School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin, 300350, China.
Research School of Chemistry, Australian National University, Canberra, 2601, Australia.
Adv Mater. 2021 Apr;33(16):e2005988. doi: 10.1002/adma.202005988. Epub 2021 Mar 12.
To improve the performance of metallic catalysts, alloying provides an efficient methodology to design state-of-the-art materials. As emerging functional materials, rare-earth metal compounds can integrate the unique orbital structure and catalytic behavior of rare earth elements into metallic materials. Such rare-earth containing alloy catalysts proffer an opportunity to tailor electronic properties, tune charged carrier transport, and synergize surface reactivity, which are expected to significantly improve the performance and stability of catalysis. Despite its significance, there are only few reviews on rare earth containing alloys or related topics. This review summarizes the composition, synthesis, and applications of rare earth containing alloys in the field of catalysis. Subsequent to comprehensively summarizing and constructively discussing the existing work, the challenges and possibilities of future research on rare-earth metal compound materials are evaluated.
为了提高金属催化剂的性能,合金化提供了一种设计先进材料的有效方法。作为新兴的功能材料,稀土金属化合物可以将稀土元素独特的轨道结构和催化行为整合到金属材料中。这种含稀土合金催化剂为调整电子性质、调节载流子传输以及协同表面反应性提供了契机,有望显著提高催化性能和稳定性。尽管其意义重大,但关于含稀土合金或相关主题的综述却很少。本综述总结了含稀土合金在催化领域的组成、合成及应用。在全面总结并建设性地讨论现有工作之后,对稀土金属复合材料未来研究的挑战和可能性进行了评估。