School of Chemistry, The University of Melbourne, Parkville, Victoria, 3010, Australia.
Chem Asian J. 2021 Apr 19;16(8):890-901. doi: 10.1002/asia.202100039. Epub 2021 Mar 22.
Coordination polymers and metal-organic frameworks are prime candidates for general chemical sensing, but the use of these porous materials as chiral probes is still an emerging field. In the last decade, they have found application in a range of chiral analysis methods, including liquid- and gas-phase chromatography, circular dichroism spectroscopy, fluorescence sensing, and NMR spectroscopy. In this minireview, we examine recent works on coordination polymers as chiral sensors and their enantioselective host-guest chemistry, while highlighting their potential for application in different settings.
配位聚合物和金属有机骨架是通用化学传感的首选候选材料，但这些多孔材料作为手性探针的应用仍然是一个新兴领域。在过去的十年中，它们已应用于一系列手性分析方法，包括液相和气相色谱、圆二色光谱、荧光传感和 NMR 光谱。在这篇综述中，我们考察了配位聚合物作为手性传感器及其对映选择性主客体化学的最新研究进展，同时强调了它们在不同应用场景中的应用潜力。
