可溶性镧系元素-过渡金属簇LnCo作为水氧化的有效分子电催化剂。
Soluble lanthanide-transition-metal clusters LnCo as effective molecular electrocatalysts for water oxidation.
作者信息
Chen Rong, Chen Chao-Long, Du Ming-Hao, Wang Xing, Wang Cheng, Long La-Sheng, Kong Xiang-Jian, Zheng Lan-Sun
机构信息
Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
出版信息
Chem Commun (Camb). 2021 Apr 14;57(29):3611-3614. doi: 10.1039/d0cc08132a. Epub 2021 Mar 16.
Here we report for the first time soluble lanthanide-transition-metal clusters LnCo (Ln = Eu, Gd and Dy) as effective homogeneous water oxidation electrocatalysts. The stable 48-metal LnCo clusters show an effective water oxidation activity under acidic conditions because of the synergistic effect between lanthanide and transition metals in O-O bond formation.
在此，我们首次报道了可溶性镧系-过渡金属簇LnCo（Ln = Eu、Gd和Dy）作为有效的均相水氧化电催化剂。稳定的48金属LnCo簇由于镧系元素和过渡金属在O-O键形成中的协同作用，在酸性条件下表现出有效的水氧化活性。
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