铑电催化的化学发散性C-H活化反应：利用亚烷基环丙烷实现选择性环丙烷化反应
Rhodaelectro-catalyzed chemo-divergent C-H activations with alkylidenecyclopropanes for selective cyclopropylations.
作者信息
Shen Zhigao, Maksso Isaac, Kuniyil Rositha, Rogge Torben, Ackermann Lutz
机构信息
Institut für Organsiche und Biomolekulare Chemie and Wöhler Research Institute for Sustainable Chemistry, Georg-August-Universität Göttingen, Tammannstrasse 2, Göttingen 37077, Germany.
出版信息
Chem Commun (Camb). 2021 Apr 18;57(30):3668-3671. doi: 10.1039/d0cc08123j. Epub 2021 Mar 16.
Herein, we report on selectivity control in C-H activations with alkylidenecyclopropanes (ACPs) for the chemo-selective assembly of cyclopropanes or dienes. Thus, unprecedented rhodaelectro-catalyzed C-H activations were realized with diversely decorated ACPs with a wide substrate scope and electricity as the sole oxidant.
在此，我们报道了利用亚烷基环丙烷（ACPs）进行C-H活化时的选择性控制，用于环丙烷或二烯烃的化学选择性组装。因此，实现了前所未有的铑电催化C-H活化，该活化使用了具有广泛底物范围且以电作为唯一氧化剂的各种修饰的ACPs。
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