Denitrification using permeable reactive barriers with organic substrate or zero-valent iron fillers: controlling mechanisms, challenges, and future perspectives.

Nitrate as a diffusive agricultural contaminant has been causing substantial groundwater quality deterioration worldwide. In situ groundwater remediation techniques using permeable reactive barriers (PRBs) have attracted increasing interest. Particularly, PRBs based on biological denitrification, using the organic substrate as a biostimulator, and chemical nitrate reduction, using zero-valent iron (ZVI) as a reductant, are two major PRB approaches for groundwater denitrification. This review paper analyzed the published studies over the past 10 years (2010-2020) using laboratory, modeling, and field-scale approaches to explore the performance and mechanisms of these two types of PRBs. Important factors affecting the denitrification efficiencies as well as the influential mechanisms were discussed. Several research gaps have been identified and further research needs are discussed in the end.