Xue Zhen-Zhen, Meng Xiang-Dong, Li Xin-Yu, Han Song-De, Pan Jie, Wang Guo-Ming
College of Chemistry and Chemical Engineering, Qingdao University, Shandong 266071, China.
Inorg Chem. 2021 Apr 5;60(7):4375-4379. doi: 10.1021/acs.inorgchem.1c00280. Epub 2021 Mar 17.
Herein, we report a -type metal-organic hybrid network based on the [AgBr] clusters and hexamethylenetetramine molecules wherein both the inorganic nodes and organic linkers feature adamantane-like geometry with a symmetry. The silver bromine complex presents a dual emission and exhibits an interesting luminescent thermochromism behavior. Remarkably, white-light emission can be readily realized through variation of the temperature. In addition, the title compound is expected to be competent as a luminescent thermometer for temperature identification.
在此，我们报道了一种基于[AgBr]簇和六亚甲基四胺分子的a型金属有机杂化网络，其中无机节点和有机连接体均具有类似金刚烷的几何结构且具有对称性。溴化银配合物呈现出双重发射，并表现出有趣的发光热致变色行为。值得注意的是，通过改变温度可以很容易地实现白光发射。此外，该标题化合物有望成为一种用于温度识别的发光温度计。
