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扩大用于生产过氧化氢的多电极微生物电合成规模。

Scaling-up of microbial electrosynthesis with multiple electrodes for production of hydrogen peroxide.

作者信息

Zou Rusen, Hasanzadeh Aliyeh, Khataee Alireza, Yang Xiaoyong, Xu Mingyi, Angelidaki Irini, Zhang Yifeng

机构信息

Department of Environmental Engineering, Technical University of Denmark, 2800 Lyngby, Denmark.

Process and Systems Engineering Center (PROSYS), Department of Chemical and Biochemical Engineering, Technical University of Denmark, Kgs. Lyngby, Denmark.

出版信息

iScience. 2021 Jan 22;24(2):102094. doi: 10.1016/j.isci.2021.102094. eCollection 2021 Feb 19.

Abstract

Microbial electrosynthesis system (MES) has recently been shown to be a promising alternative way for realizing and energy-saving synthesis of hydrogen peroxide (HO). Although promising, the scaling-up feasibility of such a process is rarely reported. In this study, a 20-L up-scaled two-chamber MES reactor was developed and investigated for and efficient HO electrosynthesis. Maximum HO production rate of 10.82 mg L h and cumulative HO concentration of 454.44 mg L within 42 h were obtained with an input voltage of 0.6 V, cathodic aeration velocity of 0.045 mL min mL, 50 mM NaSO, and initial pH 3. The electrical energy consumption regarding direct input voltage was only 0.239 kWh kg HO, which was further much lower compared with laboratory-scale systems. The obtained results suggested that the future industrialization of MES technology for synthesis of HO and further application in environmental remediation have broad prospects.

摘要

微生物电合成系统(MES)最近已被证明是实现过氧化氢(HO)节能合成的一种很有前景的替代方法。尽管前景广阔,但很少有关于这种工艺放大可行性的报道。在本研究中,开发了一个20升的放大双室MES反应器,并对其进行了高效HO电合成的研究。在输入电压为0.6 V、阴极曝气速度为0.045 mL min mL、50 mM NaSO和初始pH值为3的条件下,获得了10.82 mg L h的最大HO产率和42小时内454.44 mg L的累积HO浓度。关于直接输入电压的电能消耗仅为0.239 kWh kg HO,与实验室规模的系统相比要低得多。所得结果表明,MES技术未来用于HO合成的工业化及在环境修复中的进一步应用具有广阔前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0c0/7969820/1deccee2b66e/fx1.jpg

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