Hydrophobic Porous Polypropylene with Hierarchical Structures for Ultrafast and Highly Selective Oil/Water Separation.

Recently, various porous absorbents have been developed and the in situ vacuum/pump-assisted continuous separation process has proven to be the most efficient technique to utilize those absorbents for oil spill cleanup. However, to achieve a high oil removal throughput, a high pumping pressure and/or large absorbent pore sizes are required, which would compromise the selectivity of oil/water separation, as water may penetrate the absorbent beyond a critical external pressure. In this work, this challenge has been circumvented by employing hierarchically porous polypropylene (PP) with controlled pore sizes generated from a tricontinuous heterophase polymer blend system. As compared to unimodal pores, the incorporation of the secondary smaller pores significantly enhances the oil removal throughput by up to 4-5 times without the necessity of raising the pumping pressure or increasing the diameter of the primary pores, which in turn, prevents compromising the oil/water separation selectivity.