Ma Chunlin, Wang Yao, Zhang Jia, Hu Ying, Zhai Zhangyin, Wu Jin, Zhou Weiping, Lv Xuewei
School of Physics and Electronic Electrical Engineering, Huaiyin Normal University, Huaian 223001, People's Republic of China.
School of Physics and Electronic Electrical Engineering, Huaiyin Normal University, Huaian 223001, People's Republic of China.
Spectrochim Acta A Mol Biomol Spectrosc. 2021 Jun 5;254:119636. doi: 10.1016/j.saa.2021.119636. Epub 2021 Mar 9.
A series of Dy doped NaBiTiO (NBT: xDy, x = 0.003-0.018) lead-free ferroelectric ceramics were successfully prepared by a solid-state reaction method. The Dy ions composition dependent photoluminescence properties were systematically studied. All the samples display intense characteristic emission of Dy under an excitation wavelength of 454 nm, which are attributed to the transitions of F → H (J = 13, 11 and 9). All the samples show strong orange-yellow emission, which could be applied to warm white light hopefully. When the content of Dy is equal to 0.012, the ceramic has the optimal luminous performance. Remarkable thermal quenching of the luminous intensity ceramic occurs as the temperature is higher than initial temperature 293 K. Furthermore, Dy activated photoluminescence performance combined with the presence of ferroelectricity in the NBT host can be applied to developing non-contact optical temperature sensitive materials and other future novel optoelectronic devices.
采用固相反应法成功制备了一系列Dy掺杂的NaBiTiO₃(NBT:xDy,x = 0.003 - 0.018)无铅铁电陶瓷。系统研究了Dy离子组成对光致发光性能的影响。所有样品在454 nm激发波长下均表现出强烈的Dy特征发射,这归因于F→H(J = 13、11和9)的跃迁。所有样品均呈现出强烈的橙黄色发射,有望应用于暖白光。当Dy含量等于0.012时,陶瓷具有最佳发光性能。当温度高于初始温度293 K时,陶瓷的发光强度出现显著的热猝灭现象。此外,Dy激活的光致发光性能与NBT基质中存在的铁电性相结合,可应用于开发非接触式光学温度敏感材料和其他未来新型光电器件。