Composition and exposure characteristics of PM on subway platforms and estimates of exposure reduction by protective masks.

There is limited information on exposure to metallic constituents of fine particulate matter in subway stations. We characterized the concentrations and composition of airborne fine particulate pollution on six subway platforms in Nanjing, China in both summer and winter of 2019. A microenvironment exposure model was used to evaluate the concentrations of elements in fine particulate matter and the contribution of exposure duration (time spent in the subway station) to overall daily exposure of subway workers and commuters with and without the use of N95 respirators, surgical masks, and cotton masks. We found that airborne fine particulate pollution on station platforms was much higher than in an urban reference site of ambient air, and the same was true for metallic constituents of the particles, such as iron, copper, manganese, strontium, and vanadium. Subway workers were exposed to higher levels of these airborne metals than commuters. The average daily exposure concentration of fine particulate matter was 73.5 μg/m for subway workers and 61.8 μg/m for commuters, while the average daily exposure to iron was 15.5 μg/m for subway workers and 2.0 μg/m for commuters. Subway workers were exposed to iron, copper, manganese, and strontium/vanadium at levels approximately eight-fold, four-fold, three-fold, and two-fold greater than the exposure sustained by commuters, respectively. We calculated that wearing N95 respirators or surgical masks can reduce the exposure to these airborne metallic particles significantly for both subway workers and commuters. Overall, we estimate that personal exposure to airborne fine particulate matter on subway platforms can be reduced through the use of N95 respirators or properly fitting masks.