Applied Physics Department, University of Vigo, E.E.I., Lagoas-Marcosende, Vigo, 36310, Spain.
Department of Materials, Imperial College London, South Kensington Campus, London, SW7 2AZ, UK.
Small. 2021 May;17(18):e2100924. doi: 10.1002/smll.202100924. Epub 2021 Mar 24.
Despite corrosion being commonly seen as a problem to be avoided, applications such as batteries or biodegradable implants do benefit from corrosion-like phenomena. However, current strategies address corrosion control from a global perspective for a whole component, without considering local adaptations to functionality specifications or inhomogeneous environments. Here, a novel concept is presented: the local control and guidance of corrosion through a laser surface treatment. Immersion tests in saline solution of AZ31 magnesium alloy samples show degradation rates reduced up to 15 times with the treatment, owing to a fast passivation after the induced microstructural modifications. By controlling the treatment conditions, the degradation can be restricted to delimited regions and driven towards specific directions. The applicability of the method for the design of tailored degradation biomedical implants is demonstrated and uses for cathodic protection systems and batteries can also be anticipated.
尽管腐蚀通常被视为需要避免的问题,但电池或可生物降解植入物等应用确实受益于类似腐蚀的现象。然而,当前的策略从全局角度出发来控制整个组件的腐蚀,而不考虑针对功能规格或不均匀环境的局部适应性。在这里,提出了一个新的概念:通过激光表面处理来局部控制和引导腐蚀。在 AZ31 镁合金样品的盐溶液中进行的浸泡试验表明,处理后的降解速率降低了 15 倍,这归因于诱导微观结构改性后的快速钝化。通过控制处理条件,可以将降解限制在限定的区域并引导至特定的方向。该方法在定制降解生物医学植入物设计中的适用性得到了证明,并且可以预期它也可用于阴极保护系统和电池。