El Zayat Hossam, Nasr Peter, Sewilam Hani
Center for Applied Research on the Environment and Sustainability (CARES), School of Science and Engineering, The American University in Cairo, AUC Avenue, P.O. Box 74, New Cairo, 11835, Egypt.
Department of Engineering Hydrology, RWTH Aachen University, Mies-van-der-Rohe Strasse 17, Aachen, 52074, Germany.
Environ Sci Pollut Res Int. 2021 Aug;28(29):39938-39951. doi: 10.1007/s11356-021-13311-z. Epub 2021 Mar 25.
A fertilizer drawn forward osmosis (FDFO) process was tested for the concentration of synthetic brine using an industrial-grade fertilizer ammonium sulfate (NH)SO as the draw solution (DS), NaCl-based synthetic brine as the feed solution (FS), and a commercial forward osmosis (FO) membrane. A bench-scale investigation and a pilot-scale investigation were carried out. By using the highest possible concentration of the DS with a fixed concentration of the FS, the brine generated by reverse osmosis (RO) desalination plants was simulated. The aim of this investigation, performed in batch mode, was to assess the feasibility of using the FDFO process with the tested DS to concentrate the brine by extracting water to dilute the DS. While the main aim of the investigated process was achieving the maximum possible volume reduction of the brine, the resulting DS was further diluted to reduce the nutrients' concentration in the diluted DS to the acceptable levels producing fertilized water that can be used for fertigation. The investigation showed that the proposed process using the tested fertilizer resulted in an average water flux of 8.01 l/h/m, and a volume reduction of the brine of around 12%.
采用工业级肥料硫酸铵((NH₄)₂SO₄)作为汲取液(DS)、基于氯化钠的合成盐水作为进料液(FS)以及商用正渗透(FO)膜,对一种肥料驱动的正渗透(FDFO)工艺进行了合成盐水浓缩测试。开展了实验室规模的研究和中试规模的研究。通过在固定进料液浓度下使用尽可能高浓度的汲取液,模拟了反渗透(RO)海水淡化厂产生的盐水。本研究以分批模式进行,目的是评估使用FDFO工艺和测试的汲取液通过提取水分来稀释汲取液从而浓缩盐水的可行性。虽然所研究工艺的主要目标是实现盐水尽可能大程度的体积减少,但所得的汲取液会进一步稀释,以将稀释后汲取液中的养分浓度降低至可接受水平,从而产生可用于施肥灌溉的施肥水。研究表明,使用测试肥料的所提议工艺产生的平均水通量为8.01升/小时/平方米,盐水体积减少了约12%。