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Synthesis of 4,5-Benzotropone π Complexes of Iron, Rhodium, and Iridium and Their Potential Use in Catalytic Borrowing-Hydrogen Reactions.

作者信息

Kodama Takuya, Kawashima Yuki, Deng Zhirong, Tobisu Mamoru

机构信息

Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.

Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University, Suita, Osaka 565-0871, Japan.

出版信息

Inorg Chem. 2021 Apr 5;60(7):4332-4336. doi: 10.1021/acs.inorgchem.0c03587. Epub 2021 Mar 26.

DOI:10.1021/acs.inorgchem.0c03587
PMID:33769049
Abstract

The syntheses of rhodium, iridium, and iron π complexes bearing 4,5-benzotropone ligands are reported. X-ray crystallographic analyses revealed that a tropone core coordinates to a metal center in a η manner with a tub-form geometry. Some of the benzotropone π complexes exhibited catalytic activity for -alkylation of aniline by borrowing hydrogen.

摘要

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