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氯酸盐-亚硝酸-碘-碘化物振荡反应

The Chlorate-Nitrous Acid-Iodine-Iodide Oscillating Reaction.

作者信息

Monteiro Emily V, R Queiroz João P, Faria Roberto B

机构信息

Instituto de Química, Universidade Federal do Rio de Janeiro, Rio de Janeiro, 21941-909 RJ, Brazil.

出版信息

ACS Omega. 2021 Mar 13;6(11):7959-7965. doi: 10.1021/acsomega.1c00933. eCollection 2021 Mar 23.

DOI:10.1021/acsomega.1c00933
PMID:33778307
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7992172/
Abstract

This work presents a new oscillating reaction based on chlorate and observed in a CSTR at room temperature. This can be the first member of a new family of oscillating reactions. In addition, it is also the first oscillating reaction to use nitrous acid as a reactant. Four different behaviors were observed: simple oscillations, mixed mode oscillations, bursts, and quasiperiodicity. The period of oscillations is very short, which is around 1 s. Together with the fact that it also shows fast bursts, it opens the possibility that it can be used to simulate fast biological events, like the neuron's communications signals.

摘要

这项工作展示了一种基于氯酸盐的新型振荡反应,该反应在室温下的连续搅拌釜式反应器(CSTR)中被观察到。这可能是一个新的振荡反应家族的首个成员。此外,它也是第一个使用亚硝酸作为反应物的振荡反应。观察到了四种不同的行为:简单振荡、混合模式振荡、猝发和准周期性。振荡周期非常短,约为1秒。再加上它还表现出快速猝发这一事实,这使得它有可能被用于模拟快速的生物事件,比如神经元的通信信号。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e7d9/7992172/6158411c9907/ao1c00933_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e7d9/7992172/6dd5c5caa513/ao1c00933_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e7d9/7992172/68523d6b9ef6/ao1c00933_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e7d9/7992172/f92c24a4ed1e/ao1c00933_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e7d9/7992172/0bf2a9b23e66/ao1c00933_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e7d9/7992172/6158411c9907/ao1c00933_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e7d9/7992172/6dd5c5caa513/ao1c00933_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e7d9/7992172/68523d6b9ef6/ao1c00933_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e7d9/7992172/f92c24a4ed1e/ao1c00933_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e7d9/7992172/0bf2a9b23e66/ao1c00933_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e7d9/7992172/6158411c9907/ao1c00933_0006.jpg

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Kinetics and Mechanism of the Chlorate-Nitrous Acid Reaction.氯酸盐-亚硝酸反应的动力学与机理
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