A critical analysis of sono-hybrid advanced oxidation process of ferrioxalate system for degradation of recalcitrant pollutants.

The emerging contaminants in wastewater discharged from numerous chemical process industries, pharmaceutical industries, textile, and wineries have attracted the attention of the scientific community due to their toxicity and persistence in the environment. The conventional techniques are incompetent to treat many of such recalcitrant toxic pollutants. To achieve high mineralization, advanced oxidation processes (AOPs) are found to be more efficient for the degradation of these organic pollutants without producing secondary pollutants with no/less amount of sludge. The primary oxidation agents for AOPs are in-situ generated free radicals, which are highly reactive and effective oxidants for degrading any type of organic molecules present in the wastewater. In the past decades, the combination of AOPs or simultaneous application of more than one AOP has been investigated extensively for wastewater treatment and these hybrid-AOPs have been reported to be beneficial for high-level mineralization of organic pollutants. This paper presented the characteristics, properties and influence of parameters in sono-photo-ferrioxalate system. The primary operating parameters in sono-photo-ferrioxalate system that affect the kinetics are defined as the solution pH, temperature, molar ratio of Fe/CO, HO concentration, source of light, ultrasound intensity, dissolved gases, and size of cavitation bubble. In this process, several oxidizing radicals are generated such as HO, HO, CO, CO and O which are also responsible for degradation. In this review, we have mainly addressed the degradation of recalcitrant pollutants using the sono-photo-ferrioxalate system and a critical analysis of process parameters that influence mineralization efficiency.