• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

通过在热水中热固化减轻纳米纤维支撑的薄膜复合正渗透膜的反向盐泄漏

Alleviation of Reverse Salt Leakage across Nanofiber Supported Thin-Film Composite Forward Osmosis Membrane via Heat-Curing in Hot Water.

作者信息

Ke Xiao-Xue, Wang Ting-Yu, Wu Xiao-Qiong, Chen Jiang-Ping, Zhao Quan-Bao, Zheng Yu-Ming

机构信息

CAS Key Laboratory of Urban Pollutant Conversion, Institute of Urban Environment, Chinese Academy of Sciences, 1799 Jimei Road, Xiamen 361021, China.

University of Chinese Academy of Sciences, 19A Yuquan Road, Beijing 100049, China.

出版信息

Membranes (Basel). 2021 Mar 27;11(4):237. doi: 10.3390/membranes11040237.

DOI:10.3390/membranes11040237
PMID:33801696
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8066147/
Abstract

Electrospun nanofiber with interconnected porous structure has been studied as a promising support layer of polyamide (PA) thin-film composite (TFC) forward osmosis (FO) membrane. However, its rough surface with irregular pores is prone to the formation of a defective PA active layer after interfacial polymerization, which shows high reverse salt leakage in FO desalination. Heat-curing is beneficial for crosslinking and stabilization of the PA layer. In this work, a nanofiber-supported PA TFC membrane was conceived to be cured on a hot water surface with preserved phase interface for potential "defect repair", which could be realized by supplementary interfacial polymerization of residual monomers during heat-curing. The resultant hot-water-curing FO membrane with a more uniform superhydrophilic and highly crosslinked PA layer exhibited much lower reverse salt flux (FO: 0.3 gMH, PRO: 0.8 gMH) than that of oven-curing FO membrane (FO: 2.3 gMH, PRO: 2.2 gMH) and achieved ∼4 times higher separation efficiency. It showed superior stability owing to mitigated reverse salt leakage and osmotic pressure loss, with its water flux decline lower than a quarter that of the oven-curing membrane. This study could provide new insight into the fine-tuning of nanofiber-supported TFC FO membrane for high-quality desalination via a proper selection of heat-curing methods.

摘要

具有相互连接的多孔结构的电纺纳米纤维已被研究作为聚酰胺（PA）薄膜复合（TFC）正渗透（FO）膜的一种有前景的支撑层。然而，其具有不规则孔隙的粗糙表面在界面聚合后容易形成有缺陷的PA活性层，这在FO脱盐中表现出高的反向盐泄漏。热固化有利于PA层的交联和稳定。在这项工作中，构思了一种纳米纤维支撑的PA TFC膜在具有保留相界面的热水表面上进行固化以实现潜在的“缺陷修复”，这可以通过热固化过程中残留单体的补充界面聚合来实现。所得的具有更均匀的超亲水和高度交联PA层的热水固化FO膜表现出比烘箱固化FO膜（FO：2.3 gMH，PRO：0.8 gMH）低得多的反向盐通量（FO：0.3 gMH，PRO：0.8 gMH），并且实现了约4倍的更高分离效率。由于反向盐泄漏和渗透压损失减轻，它表现出优异的稳定性，其水通量下降低于烘箱固化膜的四分之一。这项研究可以通过适当选择热固化方法为纳米纤维支撑的TFC FO膜的精细调节以实现高质量脱盐提供新的见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/346f873c58be/membranes-11-00237-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/444f4b2cbab0/membranes-11-00237-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/6bfcc684608e/membranes-11-00237-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/591cb8a93ccf/membranes-11-00237-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/a19897a128eb/membranes-11-00237-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/bda64abf4a65/membranes-11-00237-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/96aca2de65bc/membranes-11-00237-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/752f507edb1d/membranes-11-00237-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/480d3380c14d/membranes-11-00237-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/a772bdc68d13/membranes-11-00237-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/42dc3dd2bf52/membranes-11-00237-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/346f873c58be/membranes-11-00237-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/444f4b2cbab0/membranes-11-00237-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/6bfcc684608e/membranes-11-00237-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/591cb8a93ccf/membranes-11-00237-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/a19897a128eb/membranes-11-00237-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/bda64abf4a65/membranes-11-00237-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/96aca2de65bc/membranes-11-00237-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/752f507edb1d/membranes-11-00237-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/480d3380c14d/membranes-11-00237-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/a772bdc68d13/membranes-11-00237-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/42dc3dd2bf52/membranes-11-00237-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c209/8066147/346f873c58be/membranes-11-00237-g011.jpg

相似文献

1
Alleviation of Reverse Salt Leakage across Nanofiber Supported Thin-Film Composite Forward Osmosis Membrane via Heat-Curing in Hot Water.通过在热水中热固化减轻纳米纤维支撑的薄膜复合正渗透膜的反向盐泄漏
Membranes (Basel). 2021 Mar 27;11(4):237. doi: 10.3390/membranes11040237.
2
Modification of Nanofiber Support Layer for Thin Film Composite forward Osmosis Membranes via Layer-by-Layer Polyelectrolyte Deposition.通过层层聚电解质沉积对用于薄膜复合正渗透膜的纳米纤维支撑层进行改性
Membranes (Basel). 2018 Aug 25;8(3):70. doi: 10.3390/membranes8030070.
3
High performance forward osmosis membrane with ultrathin hydrophobic nanofibrous interlayer.具有超薄疏水性纳米纤维中间层的高性能正向渗透膜。
Chemosphere. 2023 Oct;338:139556. doi: 10.1016/j.chemosphere.2023.139556. Epub 2023 Jul 17.
4
Polyoxometalate based thin film nanocomposite forward osmosis membrane: Superhydrophilic, anti-fouling, and high water permeable.基于多金属氧酸盐的薄膜纳米复合正向渗透膜：超亲水、抗污染、高水渗透性。
J Colloid Interface Sci. 2019 Feb 15;536:328-338. doi: 10.1016/j.jcis.2018.10.069. Epub 2018 Oct 23.
5
High performance nanofiber-supported thin film composite forward osmosis membranes based on continuous thermal-rolling pretreated electrospun PES/PAN blend substrates.基于连续热辊压预处理静电纺丝的 PES/PAN 共混基底的高性能纳米纤维支撑的薄膜复合正向渗透膜。
Chemosphere. 2020 Dec;261:127687. doi: 10.1016/j.chemosphere.2020.127687. Epub 2020 Jul 19.
6
Improved Forward Osmosis Performance of Thin Film Composite Membranes with Graphene Quantum Dots Derived from Eucalyptus Tree Leaves.源自桉树叶的石墨烯量子点增强复合薄膜的正向渗透性能
Nanomaterials (Basel). 2022 Oct 8;12(19):3519. doi: 10.3390/nano12193519.
7
Optimal Performance of Thin-Film Composite Nanofiltration-Like Forward Osmosis Membranes Set Off by Changing the Chemical Structure of Diamine Reacted with Trimesoyl Chloride through Interfacial Polymerization.通过界面聚合改变与均苯三甲酰氯反应的二胺的化学结构引发的类薄膜复合纳滤正向渗透膜的最佳性能
Polymers (Basel). 2021 Feb 12;13(4):544. doi: 10.3390/polym13040544.
8
Study of polyamide thin film characteristics impact on permeability/selectivity performance and fouling behavior of forward osmosis membrane.聚酰胺薄膜特性对正向渗透膜渗透/选择性性能和污染行为影响的研究。
Environ Sci Pollut Res Int. 2019 Jan;26(2):1181-1191. doi: 10.1007/s11356-017-0043-x. Epub 2017 Sep 5.
9
Preparation and Properties of Thin-Film Composite Forward Osmosis Membranes Supported by Cellulose Triacetate Porous Substrate via a Nonsolvent-Thermally Induced Phase Separation Process.通过非溶剂热致相分离过程制备的、由三醋酸纤维素多孔基材支撑的薄膜复合正渗透膜的制备及其性能
Membranes (Basel). 2022 Apr 10;12(4):412. doi: 10.3390/membranes12040412.
10
Integrating seawater desalination and wastewater reclamation forward osmosis process using thin-film composite mixed matrix membrane with functionalized carbon nanotube blended polyethersulfone support layer.采用功能化碳纳米管共混聚醚砜支撑层的薄膜复合混合基质膜实现海水淡化和废水再利用正向渗透过程的集成。
Chemosphere. 2017 Oct;185:1181-1188. doi: 10.1016/j.chemosphere.2017.06.136. Epub 2017 Jul 18.

引用本文的文献

1
Evaluating Post-Treatment Effects on Electrospun Nanofiber as a Support for Polyamide Thin-Film Formation.评估电纺纳米纤维作为聚酰胺薄膜形成支撑物的后处理效果。
Polymers (Basel). 2024 Mar 5;16(5):713. doi: 10.3390/polym16050713.
2
Novel Thin Film Nanocomposite Forward Osmosis Membranes Prepared by Organic Phase Controlled Interfacial Polymerization with Functional Multi-Walled Carbon Nanotubes.通过有机相控制界面聚合与功能化多壁碳纳米管制备的新型薄膜纳米复合正渗透膜
Membranes (Basel). 2021 Jun 28;11(7):476. doi: 10.3390/membranes11070476.

本文引用的文献

1
Strategies in Forward Osmosis Membrane Substrate Fabrication and Modification: A Review.正向渗透膜基材制备与改性策略：综述
Membranes (Basel). 2020 Nov 7;10(11):332. doi: 10.3390/membranes10110332.
2
Forward Osmosis as Concentration Process: Review of Opportunities and Challenges.作为浓缩过程的正向渗透：机遇与挑战综述
Membranes (Basel). 2020 Oct 14;10(10):284. doi: 10.3390/membranes10100284.
3
Effects of the Substrate on Interfacial Polymerization: Tuning the Hydrophobicity via Polyelectrolyte Deposition.底物对界面聚合的影响：通过聚电解质沉积调节疏水性。
Membranes (Basel). 2020 Sep 26;10(10):259. doi: 10.3390/membranes10100259.
4
Engineering a Nanocomposite Interlayer for a Novel Ceramic-Based Forward Osmosis Membrane with Enhanced Performance.工程纳米复合夹层用于新型陶瓷基正向渗透膜以提高性能。
Environ Sci Technol. 2020 Jun 16;54(12):7715-7724. doi: 10.1021/acs.est.0c02809. Epub 2020 May 28.
5
Highly permeable and highly selective ultrathin film composite polyamide membranes reinforced by reactable polymer chains.由可反应聚合物链增强的高渗透性和高选择性超薄复合聚酰胺膜。
J Colloid Interface Sci. 2019 Sep 15;552:418-425. doi: 10.1016/j.jcis.2019.05.070. Epub 2019 May 23.
6
Osmosis, from molecular insights to large-scale applications.渗透作用：从分子层面的见解到大规模应用
Chem Soc Rev. 2019 Jun 4;48(11):3102-3144. doi: 10.1039/c8cs00420j.
7
Thin Film Composite Membrane for Oily Waste Water Treatment: Recent Advances and Challenges.用于含油废水处理的复合薄膜：最新进展与挑战
Membranes (Basel). 2018 Sep 21;8(4):86. doi: 10.3390/membranes8040086.
8
Modification of Nanofiber Support Layer for Thin Film Composite forward Osmosis Membranes via Layer-by-Layer Polyelectrolyte Deposition.通过层层聚电解质沉积对用于薄膜复合正渗透膜的纳米纤维支撑层进行改性
Membranes (Basel). 2018 Aug 25;8(3):70. doi: 10.3390/membranes8030070.
9
Superior Antifouling Capability of Hydrogel Forward Osmosis Membrane for Treating Wastewaters with High Concentration of Organic Foulants.具有优越抗污染性能的水凝胶正向渗透膜用于处理高浓度有机污染物废水。
Environ Sci Technol. 2018 Feb 6;52(3):1421-1428. doi: 10.1021/acs.est.7b04838. Epub 2018 Jan 17.
10
Nanotechnology for a safe and sustainable water supply: enabling integrated water treatment and reuse.纳米技术在安全可持续供水方面的应用：实现水的综合处理与再利用。
Acc Chem Res. 2013 Mar 19;46(3):834-43. doi: 10.1021/ar300029v. Epub 2012 Jun 27.