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关于环氧树脂、不饱和聚酯树脂及其含阻燃剂的纤维织物复合材料的选择图表

Towards Selection Charts for Epoxy Resin, Unsaturated Polyester Resin and Their Fibre-Fabric Composites with Flame Retardants.

作者信息

Ramadan Noha, Taha Mohamed, La Rosa Angela Daniela, Elsabbagh Ahmed

机构信息

Design and Production Engineering Department, Ain Shams University, Abbassia, Cairo 11517, Egypt.

Department of Manufacturing and Civil Engineering, Norwegian University of Science and Technology, 7491 Trondheim, Norway.

出版信息

Materials (Basel). 2021 Mar 3;14(5):1181. doi: 10.3390/ma14051181.

Abstract

Epoxy and unsaturated polyester resins are the most used thermosetting polymers. They are commonly used in electronics, construction, marine, automotive and aircraft industries. Moreover, reinforcing both epoxy and unsaturated polyester resins with carbon or glass fibre in a fabric form has enabled them to be used in high-performance applications. However, their organic nature as any other polymeric materials made them highly flammable materials. Enhancing the flame retardancy performance of thermosetting polymers and their composites can be improved by the addition of flame-retardant materials, but this comes at the expense of their mechanical properties. In this regard, a comprehensive review on the recent research articles that studied the flame retardancy of epoxy resin, unsaturated polyester resin and their composites were covered. Flame retardancy performance of different flame retardant/polymer systems was evaluated in terms of Flame Retardancy index (FRI) that was calculated based on the data extracted from the cone calorimeter test. Furthermore, flame retardant selection charts that relate between the flame retardancy level with mechanical properties in the aspects of tensile and flexural strength were presented. This review paper is also dedicated to providing the reader with a brief overview on the combustion mechanism of polymeric materials, their flammability behaviour and the commonly used flammability testing techniques and the mechanism of action of flame retardants.

摘要

环氧树脂和不饱和聚酯树脂是最常用的热固性聚合物。它们常用于电子、建筑、船舶、汽车和航空航天工业。此外,用织物形式的碳或玻璃纤维增强环氧树脂和不饱和聚酯树脂,使它们能够用于高性能应用。然而,与任何其他聚合物材料一样,它们的有机性质使它们成为高度易燃材料。通过添加阻燃材料可以提高热固性聚合物及其复合材料的阻燃性能,但这是以牺牲它们的机械性能为代价的。在这方面,对最近研究环氧树脂、不饱和聚酯树脂及其复合材料阻燃性的研究文章进行了全面综述。根据从锥形量热仪测试中提取的数据计算出的阻燃指数(FRI),评估了不同阻燃剂/聚合物体系的阻燃性能。此外,还给出了在拉伸和弯曲强度方面将阻燃水平与机械性能联系起来的阻燃剂选择图表。这篇综述文章还致力于向读者简要概述聚合物材料的燃烧机理、它们的燃烧行为以及常用的燃烧测试技术和阻燃剂的作用机理。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/daac/7959149/40b8d2163e5e/materials-14-01181-g001.jpg

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